THE SECOND BOOK OF OPTICKS

PART I. Observations concerning the Reflexions, Refractions, and Colours of thin transparent Bodies.

It has been observed by others, that transparent Substances, as Glass, Water, Air, &c. when made very thin by being blown into Bubbles, or otherwise formed into Plates, do exhibit various Colours according to their various thinness, altho' at a greater thickness they appear very clear and colourless. In the former Book I forbore to treat of these Colours, because they seemed of a more difficult Consideration, and were not necessary for establishing the Properties of Light there discoursed of. But because they may conduce to farther Discoveries for compleating the Theory of Light, especially as to the constitution of the parts of natural Bodies, on which their Colours or Transparency depend; I have here set down an account of them. To render this Discourse short and distinct, I have first described the principal of my Observations, and then consider'd and made use of them. The Observations are these.

Obs. 1. Compressing two Prisms hard together that their sides (which by chance were a very little convex) might somewhere touch one another: I found the place in which they touched to become absolutely transparent, as if they had there been one continued piece of Glass. For when the Light fell so obliquely on the Air, which in other places was between them, as to be all reflected; it seemed in that place of contact to be wholly transmitted, insomuch that when look'd upon, it appeared like a black or dark spot, by reason that little or no sensible Light was reflected from thence, as from other places; and when looked through it seemed (as it were) a hole in that Air which was formed into a thin Plate, by being compress'd between the Glasses. And through this hole Objects that were beyond might be seen distinctly, which could not at all be seen through other parts of the Glasses where the Air was interjacent. Although the Glasses were a little convex, yet this transparent spot was of a considerable breadth, which breadth seemed principally to proceed from the yielding inwards of the parts of the Glasses, by reason of their mutual pressure. For by pressing them very hard together it would become much broader than otherwise.

Obs. 2. When the Plate of Air, by turning the Prisms about their common Axis, became so little inclined to the incident Rays, that some of them began to be transmitted, there arose in it many slender Arcs of Colours which at first were shaped almost like the Conchoid, as you see them delineated in the first Figure. And by continuing the Motion of the Prisms, these Arcs increased and bended more and more about the said transparent spot, till they were compleated into Circles or Rings incompassing it, and afterwards continually grew more and more contracted.

Fig. 1.

These Arcs at their first appearance were of a violet and blue Colour, and between them were white Arcs of Circles, which presently by continuing the Motion of the Prisms became a little tinged in their inward Limbs with red and yellow, and to their outward Limbs the blue was adjacent. So that the order of these Colours from the central dark spot, was at that time white, blue, violet; black, red, orange, yellow, white, blue, violet, &c. But the yellow and red were much fainter than the blue and violet.

The Motion of the Prisms about their Axis being continued, these Colours contracted more and more, shrinking towards the whiteness on either side of it, until they totally vanished into it. And then the Circles in those parts appear'd black and white, without any other Colours intermix'd. But by farther moving the Prisms about, the Colours again emerged out of the whiteness, the violet and blue at its inward Limb, and at its outward Limb the red and yellow. So that now their order from the central Spot was white, yellow, red; black; violet, blue, white, yellow, red, &c. contrary to what it was before.

Obs. 3. When the Rings or some parts of them appeared only black and white, they were very distinct and well defined, and the blackness seemed as intense as that of the central Spot. Also in the Borders of the Rings, where the Colours began to emerge out of the whiteness, they were pretty distinct, which made them visible to a very great multitude. I have sometimes number'd above thirty Successions (reckoning every black and white Ring for one Succession) and seen more of them, which by reason of their smalness I could not number. But in other Positions of the Prisms, at which the Rings appeared of many Colours, I could not distinguish above eight or nine of them, and the Exterior of those were very confused and dilute.

In these two Observations to see the Rings distinct, and without any other Colour than Black and white, I found it necessary to hold my Eye at a good distance from them. For by approaching nearer, although in the same inclination of my Eye to the Plane of the Rings, there emerged a bluish Colour out of the white, which by dilating it self more and more into the black, render'd the Circles less distinct, and left the white a little tinged with red and yellow. I found also by looking through a slit or oblong hole, which was narrower than the pupil of my Eye, and held close to it parallel to the Prisms, I could see the Circles much distincter and visible to a far greater number than otherwise.

Obs. 4. To observe more nicely the order of the Colours which arose out of the white Circles as the Rays became less and less inclined to the Plate of Air; I took two Object-glasses, the one a Plano-convex for a fourteen Foot Telescope, and the other a large double Convex for one of about fifty Foot; and upon this, laying the other with its plane side downwards, I pressed them slowly together, to make the Colours successively emerge in the middle of the Circles, and then slowly lifted the upper Glass from the lower to make them successively vanish again in the same place. The Colour, which by pressing the Glasses together, emerged last in the middle of the other Colours, would upon its first appearance look like a Circle of a Colour almost uniform from the circumference to the center and by compressing the Glasses still more, grow continually broader until a new Colour emerged in its center, and thereby it became a Ring encompassing that new Colour. And by compressing the Glasses still more, the diameter of this Ring would increase, and the breadth of its Orbit or Perimeter decrease until another new Colour emerged in the center of the last: And so on until a third, a fourth, a fifth, and other following new Colours successively emerged there, and became Rings encompassing the innermost Colour, the last of which was the black Spot. And, on the contrary, by lifting up the upper Glass from the lower, the diameter of the Rings would decrease, and the breadth of their Orbit increase, until their Colours reached successively to the center; and then they being of a considerable breadth, I could more easily discern and distinguish their Species than before. And by this means I observ'd their Succession and Quantity to be as followeth.

Next to the pellucid central Spot made by the contact of the Glasses succeeded blue, white, yellow, and red. The blue was so little in quantity, that I could not discern it in the Circles made by the Prisms, nor could I well distinguish any violet in it, but the yellow and red were pretty copious, and seemed about as much in extent as the white, and four or five times more than the blue. The next Circuit in order of Colours immediately encompassing these were violet, blue, green, yellow, and red: and these were all of them copious and vivid, excepting the green, which was very little in quantity, and seemed much more faint and dilute than the other Colours. Of the other four, the violet was the least in extent, and the blue less than the yellow or red. The third Circuit or Order was purple, blue, green, yellow, and red; in which the purple seemed more reddish than the violet in the former Circuit, and the green was much more conspicuous, being as brisk and copious as any of the other Colours, except the yellow, but the red began to be a little faded, inclining very much to purple. After this succeeded the fourth Circuit of green and red. The green was very copious and lively, inclining on the one side to blue, and on the other side to yellow. But in this fourth Circuit there was neither violet, blue, nor yellow, and the red was very imperfect and dirty. Also the succeeding Colours became more and more imperfect and dilute, till after three or four revolutions they ended in perfect whiteness. Their form, when the Glasses were most compress'd so as to make the black Spot appear in the center, is delineated in the second Figure; where a, b, c, d, e: f, g, h, i, k: l, m, n, o, p: q, r: s, t: v, x: y, z, denote the Colours reckon'd in order from the center, black, blue, white, yellow, red: violet, blue, green, yellow, red: purple, blue, green, yellow, red: green, red: greenish blue, red: greenish blue, pale red: greenish blue, reddish white.

Fig. 2.

Obs. 5. To determine the interval of the Glasses, or thickness of the interjacent Air, by which each Colour was produced, I measured the Diameters of the first six Rings at the most lucid part of their Orbits, and squaring them, I found their Squares to be in the arithmetical Progression of the odd Numbers, 1, 3, 5, 7, 9, 11. And since one of these Glasses was plane, and the other spherical, their Intervals at those Rings must be in the same Progression. I measured also the Diameters of the dark or faint Rings between the more lucid Colours, and found their Squares to be in the arithmetical Progression of the even Numbers, 2, 4, 6, 8, 10, 12. And it being very nice and difficult to take these measures exactly; I repeated them divers times at divers parts of the Glasses, that by their Agreement I might be confirmed in them. And the same method I used in determining some others of the following Observations.

Obs. 6. The Diameter of the sixth Ring at the most lucid part of its Orbit was 58/100 parts of an Inch, and the Diameter of the Sphere on which the double convex Object-glass was ground was about 102 Feet, and hence I gathered the thickness of the Air or Aereal Interval of the Glasses at that Ring. But some time after, suspecting that in making this Observation I had not determined the Diameter of the Sphere with sufficient accurateness, and being uncertain whether the Plano-convex Glass was truly plane, and not something concave or convex on that side which I accounted plane; and whether I had not pressed the Glasses together, as I often did, to make them touch; (For by pressing such Glasses together their parts easily yield inwards, and the Rings thereby become sensibly broader than they would be, did the Glasses keep their Figures.) I repeated the Experiment, and found the Diameter of the sixth lucid Ring about 55/100 parts of an Inch. I repeated the Experiment also with such an Object-glass of another Telescope as I had at hand. This was a double Convex ground on both sides to one and the same Sphere, and its Focus was distant from it 83-2/5 Inches. And thence, if the Sines of Incidence and Refraction of the bright yellow Light be assumed in proportion as 11 to 17, the Diameter of the Sphere to which the Glass was figured will by computation be found 182 Inches. This Glass I laid upon a flat one, so that the black Spot appeared in the middle of the Rings of Colours without any other Pressure than that of the weight of the Glass. And now measuring the Diameter of the fifth dark Circle as accurately as I could, I found it the fifth part of an Inch precisely. This Measure was taken with the points of a pair of Compasses on the upper Surface on the upper Glass, and my Eye was about eight or nine Inches distance from the Glass, almost perpendicularly over it, and the Glass was 1/6 of an Inch thick, and thence it is easy to collect that the true Diameter of the Ring between the Glasses was greater than its measur'd Diameter above the Glasses in the Proportion of 80 to 79, or thereabouts, and by consequence equal to 16/79 parts of an Inch, and its true Semi-diameter equal to 8/79 parts. Now as the Diameter of the Sphere (182 Inches) is to the Semi-diameter of this fifth dark Ring (8/79 parts of an Inch) so is this Semi-diameter to the thickness of the Air at this fifth dark Ring; which is therefore 32/567931 or 100/1774784. Parts of an Inch; and the fifth Part thereof, viz. the 1/88739 Part of an Inch, is the Thickness of the Air at the first of these dark Rings.

The same Experiment I repeated with another double convex Object-glass ground on both sides to one and the same Sphere. Its Focus was distant from it 168-1/2 Inches, and therefore the Diameter of that Sphere was 184 Inches. This Glass being laid upon the same plain Glass, the Diameter of the fifth of the dark Rings, when the black Spot in their Center appear'd plainly without pressing the Glasses, was by the measure of the Compasses upon the upper Glass 121/600 Parts of an Inch, and by consequence between the Glasses it was 1222/6000: For the upper Glass was 1/8 of an Inch thick, and my Eye was distant from it 8 Inches. And a third proportional to half this from the Diameter of the Sphere is 5/88850 Parts of an Inch. This is therefore the Thickness of the Air at this Ring, and a fifth Part thereof, viz. the 1/88850th Part of an Inch is the Thickness thereof at the first of the Rings, as above.

I tried the same Thing, by laying these Object-glasses upon flat Pieces of a broken Looking-glass, and found the same Measures of the Rings: Which makes me rely upon them till they can be determin'd more accurately by Glasses ground to larger Spheres, though in such Glasses greater care must be taken of a true Plane.

These Dimensions were taken, when my Eye was placed almost perpendicularly over the Glasses, being about an Inch, or an Inch and a quarter, distant from the incident Rays, and eight Inches distant from the Glass; so that the Rays were inclined to the Glass in an Angle of about four Degrees. Whence by the following Observation you will understand, that had the Rays been perpendicular to the Glasses, the Thickness of the Air at these Rings would have been less in the Proportion of the Radius to the Secant of four Degrees, that is, of 10000 to 10024. Let the Thicknesses found be therefore diminish'd in this Proportion, and they will become 1/88952 and 1/89063, or (to use the nearest round Number) the 1/89000th Part of an Inch. This is the Thickness of the Air at the darkest Part of the first dark Ring made by perpendicular Rays; and half this Thickness multiplied by the Progression, 1, 3, 5, 7, 9, 11, &c. gives the Thicknesses of the Air at the most luminous Parts of all the brightest Rings, viz. 1/178000, 3/178000, 5/178000, 7/178000, &c. their arithmetical Means 2/178000, 4/178000, 6/178000, &c. being its Thicknesses at the darkest Parts of all the dark ones.

Obs. 7. The Rings were least, when my Eye was placed perpendicularly over the Glasses in the Axis of the Rings: And when I view'd them obliquely they became bigger, continually swelling as I removed my Eye farther from the Axis. And partly by measuring the Diameter of the same Circle at several Obliquities of my Eye, partly by other Means, as also by making use of the two Prisms for very great Obliquities, I found its Diameter, and consequently the Thickness of the Air at its Perimeter in all those Obliquities to be very nearly in the Proportions express'd in this Table.



In the two first Columns are express'd the Obliquities of the incident and emergent Rays to the Plate of the Air, that is, their Angles of Incidence and Refraction. In the third Column the Diameter of any colour'd Ring at those Obliquities is expressed in Parts, of which ten constitute that Diameter when the Rays are perpendicular. And in the fourth Column the Thickness of the Air at the Circumference of that Ring is expressed in Parts, of which also ten constitute its Thickness when the Rays are perpendicular.

And from these Measures I seem to gather this Rule: That the Thickness of the Air is proportional to the Secant of an Angle, whose Sine is a certain mean Proportional between the Sines of Incidence and Refraction. And that mean Proportional, so far as by these Measures I can determine it, is the first of an hundred and six arithmetical mean Proportionals between those Sines counted from the bigger Sine, that is, from the Sine of Refraction when the Refraction is made out of the Glass into the Plate of Air, or from the Sine of Incidence when the Refraction is made out of the Plate of Air into the Glass.

Obs. 8. The dark Spot in the middle of the Rings increased also by the Obliquation of the Eye, although almost insensibly. But, if instead of the Object-glasses the Prisms were made use of, its Increase was more manifest when viewed so obliquely that no Colours appear'd about it. It was least when the Rays were incident most obliquely on the interjacent Air, and as the obliquity decreased it increased more and more until the colour'd Rings appear'd, and then decreased again, but not so much as it increased before. And hence it is evident, that the Transparency was not only at the absolute Contact of the Glasses, but also where they had some little Interval. I have sometimes observed the Diameter of that Spot to be between half and two fifth parts of the Diameter of the exterior Circumference of the red in the first Circuit or Revolution of Colours when view'd almost perpendicularly; whereas when view'd obliquely it hath wholly vanish'd and become opake and white like the other parts of the Glass; whence it may be collected that the Glasses did then scarcely, or not at all, touch one another, and that their Interval at the perimeter of that Spot when view'd perpendicularly was about a fifth or sixth part of their Interval at the circumference of the said red.

Obs. 9. By looking through the two contiguous Object-glasses, I found that the interjacent Air exhibited Rings of Colours, as well by transmitting Light as by reflecting it. The central Spot was now white, and from it the order of the Colours were yellowish red; black, violet, blue, white, yellow, red; violet, blue, green, yellow, red, &c. But these Colours were very faint and dilute, unless when the Light was trajected very obliquely through the Glasses: For by that means they became pretty vivid. Only the first yellowish red, like the blue in the fourth Observation, was so little and faint as scarcely to be discern'd. Comparing the colour'd Rings made by Reflexion, with these made by transmission of the Light; I found that white was opposite to black, red to blue, yellow to violet, and green to a Compound of red and violet. That is, those parts of the Glass were black when looked through, which when looked upon appeared white, and on the contrary. And so those which in one case exhibited blue, did in the other case exhibit red. And the like of the other Colours. The manner you have represented in the third Figure, where AB, CD, are the Surfaces of the Glasses contiguous at E, and the black Lines between them are their Distances in arithmetical Progression, and the Colours written above are seen by reflected Light, and those below by Light transmitted (p. 209).

Obs. 10. Wetting the Object-glasses a little at their edges, the Water crept in slowly between them, and the Circles thereby became less and the Colours more faint: Insomuch that as the Water crept along, one half of them at which it first arrived would appear broken off from the other half, and contracted into a less Room. By measuring them I found the Proportions of their Diameters to the Diameters of the like Circles made by Air to be about seven to eight, and consequently the Intervals of the Glasses at like Circles, caused by those two Mediums Water and Air, are as about three to four. Perhaps it may be a general Rule, That if any other Medium more or less dense than Water be compress'd between the Glasses, their Intervals at the Rings caused thereby will be to their Intervals caused by interjacent Air, as the Sines are which measure the Refraction made out of that Medium into Air.

Obs. 11. When the Water was between the Glasses, if I pressed the upper Glass variously at its edges to make the Rings move nimbly from one place to another, a little white Spot would immediately follow the center of them, which upon creeping in of the ambient Water into that place would presently vanish. Its appearance was such as interjacent Air would have caused, and it exhibited the same Colours. But it was not air, for where any Bubbles of Air were in the Water they would not vanish. The Reflexion must have rather been caused by a subtiler Medium, which could recede through the Glasses at the creeping in of the Water.

Obs. 12. These Observations were made in the open Air. But farther to examine the Effects of colour'd Light falling on the Glasses, I darken'd the Room, and view'd them by Reflexion of the Colours of a Prism cast on a Sheet of white Paper, my Eye being so placed that I could see the colour'd Paper by Reflexion in the Glasses, as in a Looking-glass. And by this means the Rings became distincter and visible to a far greater number than in the open Air. I have sometimes seen more than twenty of them, whereas in the open Air I could not discern above eight or nine.

Fig. 3.


Obs. 13. Appointing an Assistant to move the Prism to and fro about its Axis, that all the Colours might successively fall on that part of the Paper which I saw by Reflexion from that part of the Glasses, where the Circles appear'd, so that all the Colours might be successively reflected from the Circles to my Eye, whilst I held it immovable, I found the Circles which the red Light made to be manifestly bigger than those which were made by the blue and violet. And it was very pleasant to see them gradually swell or contract accordingly as the Colour of the Light was changed. The Interval of the Glasses at any of the Rings when they were made by the utmost red Light, was to their Interval at the same Ring when made by the utmost violet, greater than as 3 to 2, and less than as 13 to 8. By the most of my Observations it was as 14 to 9. And this Proportion seem'd very nearly the same in all Obliquities of my Eye; unless when two Prisms were made use of instead of the Object-glasses. For then at a certain great obliquity of my Eye, the Rings made by the several Colours seem'd equal, and at a greater obliquity those made by the violet would be greater than the same Rings made by the red: the Refraction of the Prism in this case causing the most refrangible Rays to fall more obliquely on that plate of the Air than the least refrangible ones. Thus the Experiment succeeded in the colour'd Light, which was sufficiently strong and copious to make the Rings sensible. And thence it may be gather'd, that if the most refrangible and least refrangible Rays had been copious enough to make the Rings sensible without the mixture of other Rays, the Proportion which here was 14 to 9 would have been a little greater, suppose 14-1/4 or 14-1/3 to 9.

Obs. 14. Whilst the Prism was turn'd about its Axis with an uniform Motion, to make all the several Colours fall successively upon the Object-glasses, and thereby to make the Rings contract and dilate: The Contraction or Dilatation of each Ring thus made by the variation of its Colour was swiftest in the red, and slowest in the violet, and in the intermediate Colours it had intermediate degrees of Celerity. Comparing the quantity of Contraction and Dilatation made by all the degrees of each Colour, I found that it was greatest in the red; less in the yellow, still less in the blue, and least in the violet. And to make as just an Estimation as I could of the Proportions of their Contractions or Dilatations, I observ'd that the whole Contraction or Dilatation of the Diameter of any Ring made by all the degrees of red, was to that of the Diameter of the same Ring made by all the degrees of violet, as about four to three, or five to four, and that when the Light was of the middle Colour between yellow and green, the Diameter of the Ring was very nearly an arithmetical Mean between the greatest Diameter of the same Ring made by the outmost red, and the least Diameter thereof made by the outmost violet: Contrary to what happens in the Colours of the oblong Spectrum made by the Refraction of a Prism, where the red is most contracted, the violet most expanded, and in the midst of all the Colours is the Confine of green and blue. And hence I seem to collect that the thicknesses of the Air between the Glasses there, where the Ring is successively made by the limits of the five principal Colours (red, yellow, green, blue, violet) in order (that is, by the extreme red, by the limit of red and yellow in the middle of the orange, by the limit of yellow and green, by the limit of green and blue, by the limit of blue and violet in the middle of the indigo, and by the extreme violet) are to one another very nearly as the sixth lengths of a Chord which found the Notes in a sixth Major, sol, la, mi, fa, sol, la. But it agrees something better with the Observation to say, that the thicknesses of the Air between the Glasses there, where the Rings are successively made by the limits of the seven Colours, red, orange, yellow, green, blue, indigo, violet in order, are to one another as the Cube Roots of the Squares of the eight lengths of a Chord, which found the Notes in an eighth, sol, la, fa, sol, la, mi, fa, sol; that is, as the Cube Roots of the Squares of the Numbers, 1, 8/9, 5/6, 3/4, 2/3, 3/5, 9/16, 1/2.

Obs. 15. These Rings were not of various Colours like those made in the open Air, but appeared all over of that prismatick Colour only with which they were illuminated. And by projecting the prismatick Colours immediately upon the Glasses, I found that the Light which fell on the dark Spaces which were between the Colour'd Rings was transmitted through the Glasses without any variation of Colour. For on a white Paper placed behind, it would paint Rings of the same Colour with those which were reflected, and of the bigness of their immediate Spaces. And from thence the origin of these Rings is manifest; namely, that the Air between the Glasses, according to its various thickness, is disposed in some places to reflect, and in others to transmit the Light of any one Colour (as you may see represented in the fourth Figure) and in the same place to reflect that of one Colour where it transmits that of another.

Fig. 4.


Obs. 16. The Squares of the Diameters of these Rings made by any prismatick Colour were in arithmetical Progression, as in the fifth Observation. And the Diameter of the sixth Circle, when made by the citrine yellow, and viewed almost perpendicularly was about 58/100 parts of an Inch, or a little less, agreeable to the sixth Observation.

The precedent Observations were made with a rarer thin Medium, terminated by a denser, such as was Air or Water compress'd between two Glasses. In those that follow are set down the Appearances of a denser Medium thin'd within a rarer, such as are Plates of Muscovy Glass, Bubbles of Water, and some other thin Substances terminated on all sides with air.

Obs. 17. If a Bubble be blown with Water first made tenacious by dissolving a little Soap in it, 'tis a common Observation, that after a while it will appear tinged with a great variety of Colours. To defend these Bubbles from being agitated by the external Air (whereby their Colours are irregularly moved one among another, so that no accurate Observation can be made of them,) as soon as I had blown any of them I cover'd it with a clear Glass, and by that means its Colours emerged in a very regular order, like so many concentrick Rings encompassing the top of the Bubble. And as the Bubble grew thinner by the continual subsiding of the Water, these Rings dilated slowly and overspread the whole Bubble, descending in order to the bottom of it, where they vanish'd successively. In the mean while, after all the Colours were emerged at the top, there grew in the center of the Rings a small round black Spot, like that in the first Observation, which continually dilated it self till it became sometimes more than 1/2 or 3/4 of an Inch in breadth before the Bubble broke. At first I thought there had been no Light reflected from the Water in that place, but observing it more curiously, I saw within it several smaller round Spots, which appeared much blacker and darker than the rest, whereby I knew that there was some Reflexion at the other places which were not so dark as those Spots. And by farther Tryal I found that I could see the Images of some things (as of a Candle or the Sun) very faintly reflected, not only from the great black Spot, but also from the little darker Spots which were within it.

Besides the aforesaid colour'd Rings there would often appear small Spots of Colours, ascending and descending up and down the sides of the Bubble, by reason of some Inequalities in the subsiding of the Water. And sometimes small black Spots generated at the sides would ascend up to the larger black Spot at the top of the Bubble, and unite with it.

Obs. 18. Because the Colours of these Bubbles were more extended and lively than those of the Air thinn'd between two Glasses, and so more easy to be distinguish'd, I shall here give you a farther description of their order, as they were observ'd in viewing them by Reflexion of the Skies when of a white Colour, whilst a black substance was placed behind the Bubble. And they were these, red, blue; red, blue; red, blue; red, green; red, yellow, green, blue, purple; red, yellow, green, blue, violet; red, yellow, white, blue, black.

The three first Successions of red and blue were very dilute and dirty, especially the first, where the red seem'd in a manner to be white. Among these there was scarce any other Colour sensible besides red and blue, only the blues (and principally the second blue) inclined a little to green.

The fourth red was also dilute and dirty, but not so much as the former three; after that succeeded little or no yellow, but a copious green, which at first inclined a little to yellow, and then became a pretty brisk and good willow green, and afterwards changed to a bluish Colour; but there succeeded neither blue nor violet.

The fifth red at first inclined very much to purple, and afterwards became more bright and brisk, but yet not very pure. This was succeeded with a very bright and intense yellow, which was but little in quantity, and soon chang'd to green: But that green was copious and something more pure, deep and lively, than the former green. After that follow'd an excellent blue of a bright Sky-colour, and then a purple, which was less in quantity than the blue, and much inclined to red.

The sixth red was at first of a very fair and lively scarlet, and soon after of a brighter Colour, being very pure and brisk, and the best of all the reds. Then after a lively orange follow'd an intense bright and copious yellow, which was also the best of all the yellows, and this changed first to a greenish yellow, and then to a greenish blue; but the green between the yellow and the blue, was very little and dilute, seeming rather a greenish white than a green. The blue which succeeded became very good, and of a very bright Sky-colour, but yet something inferior to the former blue; and the violet was intense and deep with little or no redness in it. And less in quantity than the blue.

In the last red appeared a tincture of scarlet next to violet, which soon changed to a brighter Colour, inclining to an orange; and the yellow which follow'd was at first pretty good and lively, but afterwards it grew more dilute until by degrees it ended in perfect whiteness. And this whiteness, if the Water was very tenacious and well-temper'd, would slowly spread and dilate it self over the greater part of the Bubble; continually growing paler at the top, where at length it would crack in many places, and those cracks, as they dilated, would appear of a pretty good, but yet obscure and dark Sky-colour; the white between the blue Spots diminishing, until it resembled the Threds of an irregular Net-work, and soon after vanish'd, and left all the upper part of the Bubble of the said dark blue Colour. And this Colour, after the aforesaid manner, dilated it self downwards, until sometimes it hath overspread the whole Bubble. In the mean while at the top, which was of a darker blue than the bottom, and appear'd also full of many round blue Spots, something darker than the rest, there would emerge one or more very black Spots, and within those, other Spots of an intenser blackness, which I mention'd in the former Observation; and these continually dilated themselves until the Bubble broke.

If the Water was not very tenacious, the black Spots would break forth in the white, without any sensible intervention of the blue. And sometimes they would break forth within the precedent yellow, or red, or perhaps within the blue of the second order, before the intermediate Colours had time to display themselves.

By this description you may perceive how great an affinity these Colours have with those of Air described in the fourth Observation, although set down in a contrary order, by reason that they begin to appear when the Bubble is thickest, and are most conveniently reckon'd from the lowest and thickest part of the Bubble upwards.

Obs. 19. Viewing in several oblique Positions of my Eye the Rings of Colours emerging on the top of the Bubble, I found that they were sensibly dilated by increasing the obliquity, but yet not so much by far as those made by thinn'd Air in the seventh Observation. For there they were dilated so much as, when view'd most obliquely, to arrive at a part of the Plate more than twelve times thicker than that where they appear'd when viewed perpendicularly; whereas in this case the thickness of the Water, at which they arrived when viewed most obliquely, was to that thickness which exhibited them by perpendicular Rays, something less than as 8 to 5. By the best of my Observations it was between 15 and 15-1/2 to 10; an increase about 24 times less than in the other case.

Sometimes the Bubble would become of an uniform thickness all over, except at the top of it near the black Spot, as I knew, because it would exhibit the same appearance of Colours in all Positions of the Eye. And then the Colours which were seen at its apparent circumference by the obliquest Rays, would be different from those that were seen in other places, by Rays less oblique to it. And divers Spectators might see the same part of it of differing Colours, by viewing it at very differing Obliquities. Now observing how much the Colours at the same places of the Bubble, or at divers places of equal thickness, were varied by the several Obliquities of the Rays; by the assistance of the 4th, 14th, 16th and 18th Observations, as they are hereafter explain'd, I collect the thickness of the Water requisite to exhibit any one and the same Colour, at several Obliquities, to be very nearly in the Proportion expressed in this Table.

In the two first Columns are express'd the Obliquities of the Rays to the Superficies of the Water, that is, their Angles of Incidence and Refraction. Where I suppose, that the Sines which measure them are in round Numbers, as 3 to 4, though probably the Dissolution of Soap in the Water, may a little alter its refractive Virtue. In the third Column, the Thickness of the Bubble, at which any one Colour is exhibited in those several Obliquities, is express'd in Parts, of which ten constitute its Thickness when the Rays are perpendicular. And the Rule found by the seventh Observation agrees well with these Measures, if duly apply'd; namely, that the Thickness of a Plate of Water requisite to exhibit one and the same Colour at several Obliquities of the Eye, is proportional to the Secant of an Angle, whose Sine is the first of an hundred and six arithmetical mean Proportionals between the Sines of Incidence and Refraction counted from the lesser Sine, that is, from the Sine of Refraction when the Refraction is made out of Air into Water, otherwise from the Sine of Incidence.

I have sometimes observ'd, that the Colours which arise on polish'd Steel by heating it, or on Bell-metal, and some other metalline Substances, when melted and pour'd on the Ground, where they may cool in the open Air, have, like the Colours of Water-bubbles, been a little changed by viewing them at divers Obliquities, and particularly that a deep blue, or violet, when view'd very obliquely, hath been changed to a deep red. But the Changes of these Colours are not so great and sensible as of those made by Water. For the Scoria, or vitrified Part of the Metal, which most Metals when heated or melted do continually protrude, and send out to their Surface, and which by covering the Metals in form of a thin glassy Skin, causes these Colours, is much denser than Water; and I find that the Change made by the Obliquation of the Eye is least in Colours of the densest thin Substances.

Obs. 20. As in the ninth Observation, so here, the Bubble, by transmitted Light, appear'd of a contrary Colour to that, which it exhibited by Reflexion. Thus when the Bubble being look'd on by the Light of the Clouds reflected from it, seemed red at its apparent Circumference, if the Clouds at the same time, or immediately after, were view'd through it, the Colour at its Circumference would be blue. And, on the contrary, when by reflected Light it appeared blue, it would appear red by transmitted Light.

Obs. 21. By wetting very thin Plates of Muscovy Glass, whose thinness made the like Colours appear, the Colours became more faint and languid, especially by wetting the Plates on that side opposite to the Eye: But I could not perceive any variation of their Species. So then the thickness of a Plate requisite to produce any Colour, depends only on the density of the Plate, and not on that of the ambient Medium. And hence, by the 10th and 16th Observations, may be known the thickness which Bubbles of Water, or Plates of Muscovy Glass, or other Substances, have at any Colour produced by them.

Obs. 22. A thin transparent Body, which is denser than its ambient Medium, exhibits more brisk and vivid Colours than that which is so much rarer; as I have particularly observed in the Air and Glass. For blowing Glass very thin at a Lamp Furnace, those Plates encompassed with Air did exhibit Colours much more vivid than those of Air made thin between two Glasses.

Obs. 23. Comparing the quantity of Light reflected from the several Rings, I found that it was most copious from the first or inmost, and in the exterior Rings became gradually less and less. Also the whiteness of the first Ring was stronger than that reflected from those parts of the thin Medium or Plate which were without the Rings; as I could manifestly perceive by viewing at a distance the Rings made by the two Object-glasses; or by comparing two Bubbles of Water blown at distant Times, in the first of which the Whiteness appear'd, which succeeded all the Colours, and in the other, the Whiteness which preceded them all.

Obs. 24. When the two Object-glasses were lay'd upon one another, so as to make the Rings of the Colours appear, though with my naked Eye I could not discern above eight or nine of those Rings, yet by viewing them through a Prism I have seen a far greater Multitude, insomuch that I could number more than forty, besides many others, that were so very small and close together, that I could not keep my Eye steady on them severally so as to number them, but by their Extent I have sometimes estimated them to be more than an hundred. And I believe the Experiment may be improved to the Discovery of far greater Numbers. For they seem to be really unlimited, though visible only so far as they can be separated by the Refraction of the Prism, as I shall hereafter explain.

Fig. 5.

But it was but one side of these Rings, namely, that towards which the Refraction was made, which by that Refraction was render'd distinct, and the other side became more confused than when view'd by the naked Eye, insomuch that there I could not discern above one or two, and sometimes none of those Rings, of which I could discern eight or nine with my naked Eye. And their Segments or Arcs, which on the other side appear'd so numerous, for the most part exceeded not the third Part of a Circle. If the Refraction was very great, or the Prism very distant from the Object-glasses, the middle Part of those Arcs became also confused, so as to disappear and constitute an even Whiteness, whilst on either side their Ends, as also the whole Arcs farthest from the Center, became distincter than before, appearing in the Form as you see them design'd in the fifth Figure.

The Arcs, where they seem'd distinctest, were only white and black successively, without any other Colours intermix'd. But in other Places there appeared Colours, whose Order was inverted by the refraction in such manner, that if I first held the Prism very near the Object-glasses, and then gradually removed it farther off towards my Eye, the Colours of the 2d, 3d, 4th, and following Rings, shrunk towards the white that emerged between them, until they wholly vanish'd into it at the middle of the Arcs, and afterwards emerged again in a contrary Order. But at the Ends of the Arcs they retain'd their Order unchanged.

I have sometimes so lay'd one Object-glass upon the other, that to the naked Eye they have all over seem'd uniformly white, without the least Appearance of any of the colour'd Rings; and yet by viewing them through a Prism, great Multitudes of those Rings have discover'd themselves. And in like manner Plates of Muscovy Glass, and Bubbles of Glass blown at a Lamp-Furnace, which were not so thin as to exhibit any Colours to the naked Eye, have through the Prism exhibited a great Variety of them ranged irregularly up and down in the Form of Waves. And so Bubbles of Water, before they began to exhibit their Colours to the naked Eye of a Bystander, have appeared through a Prism, girded about with many parallel and horizontal Rings; to produce which Effect, it was necessary to hold the Prism parallel, or very nearly parallel to the Horizon, and to dispose it so that the Rays might be refracted upwards.

PART II. Remarks upon the foregoing Observations.

Having given my Observations of these Colours, before I make use of them to unfold the Causes of the Colours of natural Bodies, it is convenient that by the simplest of them, such as are the 2d, 3d, 4th, 9th, 12th, 18th, 20th, and 24th, I first explain the more compounded. And first to shew how the Colours in the fourth and eighteenth Observations are produced, let there be taken in any Right Line from the Point Y, [in Fig. 6.] the Lengths YA, YB, YC, YD, YE, YF, YG, YH, in proportion to one another, as the Cube-Roots of the Squares of the Numbers, 1/2, 9/16, 3/5, 2/3, 3/4, 5/6, 8/9, 1, whereby the Lengths of a Musical Chord to sound all the Notes in an eighth are represented; that is, in the Proportion of the Numbers 6300, 6814, 7114, 7631, 8255, 8855, 9243, 10000. And at the Points A, B, C, D, E, F, G, H, let Perpendiculars Aα, Bβ, &c. be erected, by whose Intervals the Extent of the several Colours set underneath against them, is to be represented. Then divide the Line in such Proportion as the Numbers 1, 2, 3, 5, 6, 7, 9, 10, 11, &c. set at the Points of Division denote. And through those Divisions from Y draw Lines 1I, 2K, 3L, 5M, 6N, 7O, &c.

Now, if A2 be supposed to represent the Thickness of any thin transparent Body, at which the outmost Violet is most copiously reflected in the first Ring, or Series of Colours, then by the 13th Observation, HK will represent its Thickness, at which the utmost Red is most copiously reflected in the same Series. Also by the 5th and 16th Observations, A6 and HN will denote the Thicknesses at which those extreme Colours are most copiously reflected in the second Series, and A10 and HQ the Thicknesses at which they are most copiously reflected in the third Series, and so on. And the Thickness at which any of the intermediate Colours are reflected most copiously, will, according to the 14th Observation, be defined by the distance of the Line AH from the intermediate parts of the Lines 2K, 6N, 10Q, &c. against which the Names of those Colours are written below.

Fig. 6.


But farther, to define the Latitude of these Colours in each Ring or Series, let A1 design the least thickness, and A3 the greatest thickness, at which the extreme violet in the first Series is reflected, and let HI, and HL, design the like limits for the extreme red, and let the intermediate Colours be limited by the intermediate parts of the Lines 1I, and 3L, against which the Names of those Colours are written, and so on: But yet with this caution, that the Reflexions be supposed strongest at the intermediate Spaces, 2K, 6N, 10Q, &c. and from thence to decrease gradually towards these limits, 1I, 3L, 5M, 7O, &c. on either side; where you must not conceive them to be precisely limited, but to decay indefinitely. And whereas I have assign'd the same Latitude to every Series, I did it, because although the Colours in the first Series seem to be a little broader than the rest, by reason of a stronger Reflexion there, yet that inequality is so insensible as scarcely to be determin'd by Observation.

Now according to this Description, conceiving that the Rays originally of several Colours are by turns reflected at the Spaces 1I, L3, 5M, O7, 9PR11, &c. and transmitted at the Spaces AHI1, 3LM5, 7OP9, &c. it is easy to know what Colour must in the open Air be exhibited at any thickness of a transparent thin Body. For if a Ruler be applied parallel to AH, at that distance from it by which the thickness of the Body is represented, the alternate Spaces 1IL3, 5MO7, &c. which it crosseth will denote the reflected original Colours, of which the Colour exhibited in the open Air is compounded. Thus if the constitution of the green in the third Series of Colours be desired, apply the Ruler as you see at πρσφ, and by its passing through some of the blue at π and yellow at σ, as well as through the green at ρ, you may conclude that the green exhibited at that thickness of the Body is principally constituted of original green, but not without a mixture of some blue and yellow.

By this means you may know how the Colours from the center of the Rings outward ought to succeed in order as they were described in the 4th and 18th Observations. For if you move the Ruler gradually from AH through all distances, having pass'd over the first Space which denotes little or no Reflexion to be made by thinnest Substances, it will first arrive at 1 the violet, and then very quickly at the blue and green, which together with that violet compound blue, and then at the yellow and red, by whose farther addition that blue is converted into whiteness, which whiteness continues during the transit of the edge of the Ruler from I to 3, and after that by the successive deficience of its component Colours, turns first to compound yellow, and then to red, and last of all the red ceaseth at L. Then begin the Colours of the second Series, which succeed in order during the transit of the edge of the Ruler from 5 to O, and are more lively than before, because more expanded and severed. And for the same reason instead of the former white there intercedes between the blue and yellow a mixture of orange, yellow, green, blue and indigo, all which together ought to exhibit a dilute and imperfect green. So the Colours of the third Series all succeed in order; first, the violet, which a little interferes with the red of the second order, and is thereby inclined to a reddish purple; then the blue and green, which are less mix'd with other Colours, and consequently more lively than before, especially the green: Then follows the yellow, some of which towards the green is distinct and good, but that part of it towards the succeeding red, as also that red is mix'd with the violet and blue of the fourth Series, whereby various degrees of red very much inclining to purple are compounded. This violet and blue, which should succeed this red, being mixed with, and hidden in it, there succeeds a green. And this at first is much inclined to blue, but soon becomes a good green, the only unmix'd and lively Colour in this fourth Series. For as it verges towards the yellow, it begins to interfere with the Colours of the fifth Series, by whose mixture the succeeding yellow and red are very much diluted and made dirty, especially the yellow, which being the weaker Colour is scarce able to shew it self. After this the several Series interfere more and more, and their Colours become more and more intermix'd, till after three or four more revolutions (in which the red and blue predominate by turns) all sorts of Colours are in all places pretty equally blended, and compound an even whiteness.

And since by the 15th Observation the Rays endued with one Colour are transmitted, where those of another Colour are reflected, the reason of the Colours made by the transmitted Light in the 9th and 20th Observations is from hence evident.

If not only the Order and Species of these Colours, but also the precise thickness of the Plate, or thin Body at which they are exhibited, be desired in parts of an Inch, that may be also obtained by assistance of the 6th or 16th Observations. For according to those Observations the thickness of the thinned Air, which between two Glasses exhibited the most luminous parts of the first six Rings were 1/178000, 3/178000, 5/178000, 7/178000, 9/178000, 11/178000 parts of an Inch. Suppose the Light reflected most copiously at these thicknesses be the bright citrine yellow, or confine of yellow and orange, and these thicknesses will be Fλ, Fμ, Fυ, Fξ, Fο, Fτ. And this being known, it is easy to determine what thickness of Air is represented by Gφ, or by any other distance of the Ruler from AH.

But farther, since by the 10th Observation the thickness of Air was to the thickness of Water, which between the same Glasses exhibited the same Colour, as 4 to 3, and by the 21st Observation the Colours of thin Bodies are not varied by varying the ambient Medium; the thickness of a Bubble of Water, exhibiting any Colour, will be 3/4 of the thickness of Air producing the same Colour. And so according to the same 10th and 21st Observations, the thickness of a Plate of Glass, whose Refraction of the mean refrangible Ray, is measured by the proportion of the Sines 31 to 20, may be 20/31 of the thickness of Air producing the same Colours; and the like of other Mediums. I do not affirm, that this proportion of 20 to 31, holds in all the Rays; for the Sines of other sorts of Rays have other Proportions. But the differences of those Proportions are so little that I do not here consider them. On these Grounds I have composed the following Table, wherein the thickness of Air, Water, and Glass, at which each Colour is most intense and specifick, is expressed in parts of an Inch divided into ten hundred thousand equal parts.

Now if this Table be compared with the 6th Scheme, you will there see the constitution of each Colour, as to its Ingredients, or the original Colours of which it is compounded, and thence be enabled to judge of its Intenseness or Imperfection; which may suffice in explication of the 4th and 18th Observations, unless it be farther desired to delineate the manner how the Colours appear, when the two Object-glasses are laid upon one another. To do which, let there be described a large Arc of a Circle, and a streight Line which may touch that Arc, and parallel to that Tangent several occult Lines, at such distances from it, as the Numbers set against the several Colours in the Table denote. For the Arc, and its Tangent, will represent the Superficies of the Glasses terminating the interjacent Air; and the places where the occult Lines cut the Arc will show at what distances from the center, or Point of contact, each Colour is reflected.

The thickness of colour'd Plates and Particles of

There are also other Uses of this Table: For by its assistance the thickness of the Bubble in the 19th Observation was determin'd by the Colours which it exhibited. And so the bigness of the parts of natural Bodies may be conjectured by their Colours, as shall be hereafter shewn. Also, if two or more very thin Plates be laid one upon another, so as to compose one Plate equalling them all in thickness, the resulting Colour may be hereby determin'd. For instance, Mr. Hook observed, as is mentioned in his Micrographia, that a faint yellow Plate of Muscovy Glass laid upon a blue one, constituted a very deep purple. The yellow of the first Order is a faint one, and the thickness of the Plate exhibiting it, according to the Table is 4-3/5, to which add 9, the thickness exhibiting blue of the second Order, and the Sum will be 13-3/5, which is the thickness exhibiting the purple of the third Order.

To explain, in the next place, the circumstances of the 2d and 3d Observations; that is, how the Rings of the Colours may (by turning the Prisms about their common Axis the contrary way to that expressed in those Observations) be converted into white and black Rings, and afterwards into Rings of Colours again, the Colours of each Ring lying now in an inverted order; it must be remember'd, that those Rings of Colours are dilated by the obliquation of the Rays to the Air which intercedes the Glasses, and that according to the Table in the 7th Observation, their Dilatation or Increase of their Diameter is most manifest and speedy when they are obliquest. Now the Rays of yellow being more refracted by the first Superficies of the said Air than those of red, are thereby made more oblique to the second Superficies, at which they are reflected to produce the colour'd Rings, and consequently the yellow Circle in each Ring will be more dilated than the red; and the Excess of its Dilatation will be so much the greater, by how much the greater is the obliquity of the Rays, until at last it become of equal extent with the red of the same Ring. And for the same reason the green, blue and violet, will be also so much dilated by the still greater obliquity of their Rays, as to become all very nearly of equal extent with the red, that is, equally distant from the center of the Rings. And then all the Colours of the same Ring must be co-incident, and by their mixture exhibit a white Ring. And these white Rings must have black and dark Rings between them, because they do not spread and interfere with one another, as before. And for that reason also they must become distincter, and visible to far greater numbers. But yet the violet being obliquest will be something more dilated, in proportion to its extent, than the other Colours, and so very apt to appear at the exterior Verges of the white.

Afterwards, by a greater obliquity of the Rays, the violet and blue become more sensibly dilated than the red and yellow, and so being farther removed from the center of the Rings, the Colours must emerge out of the white in an order contrary to that which they had before; the violet and blue at the exterior Limbs of each Ring, and the red and yellow at the interior. And the violet, by reason of the greatest obliquity of its Rays, being in proportion most of all expanded, will soonest appear at the exterior Limb of each white Ring, and become more conspicuous than the rest. And the several Series of Colours belonging to the several Rings, will, by their unfolding and spreading, begin again to interfere, and thereby render the Rings less distinct, and not visible to so great numbers.

If instead of the Prisms the Object-glasses be made use of, the Rings which they exhibit become not white and distinct by the obliquity of the Eye, by reason that the Rays in their passage through that Air which intercedes the Glasses are very nearly parallel to those Lines in which they were first incident on the Glasses, and consequently the Rays endued with several Colours are not inclined one more than another to that Air, as it happens in the Prisms.

There is yet another circumstance of these Experiments to be consider'd, and that is why the black and white Rings which when view'd at a distance appear distinct, should not only become confused by viewing them near at hand, but also yield a violet Colour at both the edges of every white Ring. And the reason is, that the Rays which enter the Eye at several parts of the Pupil, have several Obliquities to the Glasses, and those which are most oblique, if consider'd apart, would represent the Rings bigger than those which are the least oblique. Whence the breadth of the Perimeter of every white Ring is expanded outwards by the obliquest Rays, and inwards by the least oblique. And this Expansion is so much the greater by how much the greater is the difference of the Obliquity; that is, by how much the Pupil is wider, or the Eye nearer to the Glasses. And the breadth of the violet must be most expanded, because the Rays apt to excite a Sensation of that Colour are most oblique to a second or farther Superficies of the thinn'd Air at which they are reflected, and have also the greatest variation of Obliquity, which makes that Colour soonest emerge out of the edges of the white. And as the breadth of every Ring is thus augmented, the dark Intervals must be diminish'd, until the neighbouring Rings become continuous, and are blended, the exterior first, and then those nearer the center; so that they can no longer be distinguish'd apart, but seem to constitute an even and uniform whiteness.

Among all the Observations there is none accompanied with so odd circumstances as the twenty-fourth. Of those the principal are, that in thin Plates, which to the naked Eye seem of an even and uniform transparent whiteness, without any terminations of Shadows, the Refraction of a Prism should make Rings of Colours appear, whereas it usually makes Objects appear colour'd only there where they are terminated with Shadows, or have parts unequally luminous; and that it should make those Rings exceedingly distinct and white, although it usually renders Objects confused and coloured. The Cause of these things you will understand by considering, that all the Rings of Colours are really in the Plate, when view'd with the naked Eye, although by reason of the great breadth of their Circumferences they so much interfere and are blended together, that they seem to constitute an uniform whiteness. But when the Rays pass through the Prism to the Eye, the Orbits of the several Colours in every Ring are refracted, some more than others, according to their degrees of Refrangibility: By which means the Colours on one side of the Ring (that is in the circumference on one side of its center), become more unfolded and dilated, and those on the other side more complicated and contracted. And where by a due Refraction they are so much contracted, that the several Rings become narrower than to interfere with one another, they must appear distinct, and also white, if the constituent Colours be so much contracted as to be wholly co-incident. But on the other side, where the Orbit of every Ring is made broader by the farther unfolding of its Colours, it must interfere more with other Rings than before, and so become less distinct.

Fig. 7.

To explain this a little farther, suppose the concentrick Circles AV, and BX, [in Fig. 7.] represent the red and violet of any Order, which, together with the intermediate Colours, constitute any one of these Rings. Now these being view'd through a Prism, the violet Circle BX, will, by a greater Refraction, be farther translated from its place than the red AV, and so approach nearer to it on that side of the Circles, towards which the Refractions are made. For instance, if the red be translated to av, the violet may be translated to bx, so as to approach nearer to it at x than before; and if the red be farther translated to av, the violet may be so much farther translated to bx as to convene with it at x; and if the red be yet farther translated to αΥ, the violet may be still so much farther translated to βξ as to pass beyond it at ξ, and convene with it at e and f. And this being understood not only of the red and violet, but of all the other intermediate Colours, and also of every revolution of those Colours, you will easily perceive how those of the same revolution or order, by their nearness at xv and Υξ, and their coincidence at xv, e and f, ought to constitute pretty distinct Arcs of Circles, especially at xv, or at e and f; and that they will appear severally at xυ and at xv exhibit whiteness by their coincidence, and again appear severally at Υξ, but yet in a contrary order to that which they had before, and still retain beyond e and f. But on the other side, at ab, ab, or αβ, these Colours must become much more confused by being dilated and spread so as to interfere with those of other Orders. And the same confusion will happen at Υξ between e and f, if the Refraction be very great, or the Prism very distant from the Object-glasses: In which case no parts of the Rings will be seen, save only two little Arcs at e and f, whose distance from one another will be augmented by removing the Prism still farther from the Object-glasses: And these little Arcs must be distinctest and whitest at their middle, and at their ends, where they begin to grow confused, they must be colour'd. And the Colours at one end of every Arc must be in a contrary order to those at the other end, by reason that they cross in the intermediate white; namely, their ends, which verge towards Υξ, will be red and yellow on that side next the center, and blue and violet on the other side. But their other ends which verge from Υξ, will on the contrary be blue and violet on that side towards the center, and on the other side red and yellow.

Now as all these things follow from the properties of Light by a mathematical way of reasoning, so the truth of them may be manifested by Experiments. For in a dark Room, by viewing these Rings through a Prism, by reflexion of the several prismatick Colours, which an assistant causes to move to and fro upon a Wall or Paper from whence they are reflected, whilst the Spectator's Eye, the Prism, and the Object-glasses, (as in the 13th Observation,) are placed steady; the Position of the Circles made successively by the several Colours, will be found such, in respect of one another, as I have described in the Figures abxv, or abxv, or αβξΥ. And by the same method the truth of the Explications of other Observations may be examined.

By what hath been said, the like Phænomena of Water and thin Plates of Glass may be understood. But in small fragments of those Plates there is this farther observable, that where they lie flat upon a Table, and are turned about their centers whilst they are view'd through a Prism, they will in some postures exhibit Waves of various Colours; and some of them exhibit these Waves in one or two Positions only, but the most of them do in all Positions exhibit them, and make them for the most part appear almost all over the Plates. The reason is, that the Superficies of such Plates are not even, but have many Cavities and Swellings, which, how shallow soever, do a little vary the thickness of the Plate. For at the several sides of those Cavities, for the Reasons newly described, there ought to be produced Waves in several postures of the Prism. Now though it be but some very small and narrower parts of the Glass, by which these Waves for the most part are caused, yet they may seem to extend themselves over the whole Glass, because from the narrowest of those parts there are Colours of several Orders, that is, of several Rings, confusedly reflected, which by Refraction of the Prism are unfolded, separated, and, according to their degrees of Refraction, dispersed to several places, so as to constitute so many several Waves, as there were divers orders of Colours promiscuously reflected from that part of the Glass.

These are the principal Phænomena of thin Plates or Bubbles, whose Explications depend on the properties of Light, which I have heretofore deliver'd. And these you see do necessarily follow from them, and agree with them, even to their very least circumstances; and not only so, but do very much tend to their proof. Thus, by the 24th Observation it appears, that the Rays of several Colours, made as well by thin Plates or Bubbles, as by Refractions of a Prism, have several degrees of Refrangibility; whereby those of each order, which at the reflexion from the Plate or Bubble are intermix'd with those of other orders, are separated from them by Refraction, and associated together so as to become visible by themselves like Arcs of Circles. For if the Rays were all alike refrangible, 'tis impossible that the whiteness, which to the naked Sense appears uniform, should by Refraction have its parts transposed and ranged into those black and white Arcs.

It appears also that the unequal Refractions of difform Rays proceed not from any contingent irregularities; such as are Veins, an uneven Polish, or fortuitous Position of the Pores of Glass; unequal and casual Motions in the Air or Æther, the spreading, breaking, or dividing the same Ray into many diverging parts; or the like. For, admitting any such irregularities, it would be impossible for Refractions to render those Rings so very distinct, and well defined, as they do in the 24th Observation. It is necessary therefore that every Ray have its proper and constant degree of Refrangibility connate with it, according to which its refraction is ever justly and regularly perform'd; and that several Rays have several of those degrees.

And what is said of their Refrangibility may be also understood of their Reflexibility, that is, of their Dispositions to be reflected, some at a greater, and others at a less thickness of thin Plates or Bubbles; namely, that those Dispositions are also connate with the Rays, and immutable; as may appear by the 13th, 14th, and 15th Observations, compared with the fourth and eighteenth.

By the Precedent Observations it appears also, that whiteness is a dissimilar mixture of all Colours, and that Light is a mixture of Rays endued with all those Colours. For, considering the multitude of the Rings of Colours in the 3d, 12th, and 24th Observations, it is manifest, that although in the 4th and 18th Observations there appear no more than eight or nine of those Rings, yet there are really a far greater number, which so much interfere and mingle with one another, as after those eight or nine revolutions to dilute one another wholly, and constitute an even and sensibly uniform whiteness. And consequently that whiteness must be allow'd a mixture of all Colours, and the Light which conveys it to the Eye must be a mixture of Rays endued with all those Colours.

But farther; by the 24th Observation it appears, that there is a constant relation between Colours and Refrangibility; the most refrangible Rays being violet, the least refrangible red, and those of intermediate Colours having proportionably intermediate degrees of Refrangibility. And by the 13th, 14th, and 15th Observations, compared with the 4th or 18th there appears to be the same constant relation between Colour and Reflexibility; the violet being in like circumstances reflected at least thicknesses of any thin Plate or Bubble, the red at greatest thicknesses, and the intermediate Colours at intermediate thicknesses. Whence it follows, that the colorifick Dispositions of Rays are also connate with them, and immutable; and by consequence, that all the Productions and Appearances of Colours in the World are derived, not from any physical Change caused in Light by Refraction or Reflexion, but only from the various Mixtures or Separations of Rays, by virtue of their different Refrangibility or Reflexibility. And in this respect the Science of Colours becomes a Speculation as truly mathematical as any other part of Opticks. I mean, so far as they depend on the Nature of Light, and are not produced or alter'd by the Power of Imagination, or by striking or pressing the Eye.

PART III. Of the permanent Colours of natural Bodies, and the Analogy between them and the Colours of thin transparent Plates.

I am now come to another part of this Design, which is to consider how the Phænomena of thin transparent Plates stand related to those of all other natural Bodies. Of these Bodies I have already told you that they appear of divers Colours, accordingly as they are disposed to reflect most copiously the Rays originally endued with those Colours. But their Constitutions, whereby they reflect some Rays more copiously than others, remain to be discover'd; and these I shall endeavour to manifest in the following Propositions.

Prop. I.

Those Superficies of transparent Bodies reflect the greatest quantity of Light, which have the greatest refracting Power; that is, which intercede Mediums that differ most in their refractive Densities. And in the Confines of equally refracting Mediums there is no Reflexion.

The Analogy between Reflexion and Refraction will appear by considering, that when Light passeth obliquely out of one Medium into another which refracts from the perpendicular, the greater is the difference of their refractive Density, the less Obliquity of Incidence is requisite to cause a total Reflexion. For as the Sines are which measure the Refraction, so is the Sine of Incidence at which the total Reflexion begins, to the Radius of the Circle; and consequently that Angle of Incidence is least where there is the greatest difference of the Sines. Thus in the passing of Light out of Water into Air, where the Refraction is measured by the Ratio of the Sines 3 to 4, the total Reflexion begins when the Angle of Incidence is about 48 Degrees 35 Minutes. In passing out of Glass into Air, where the Refraction is measured by the Ratio of the Sines 20 to 31, the total Reflexion begins when the Angle of Incidence is 40 Degrees 10 Minutes; and so in passing out of Crystal, or more strongly refracting Mediums into Air, there is still a less obliquity requisite to cause a total reflexion. Superficies therefore which refract most do soonest reflect all the Light which is incident on them, and so must be allowed most strongly reflexive.

But the truth of this Proposition will farther appear by observing, that in the Superficies interceding two transparent Mediums, (such as are Air, Water, Oil, common Glass, Crystal, metalline Glasses, Island Glasses, white transparent Arsenick, Diamonds, &c.) the Reflexion is stronger or weaker accordingly, as the Superficies hath a greater or less refracting Power. For in the Confine of Air and Sal-gem 'tis stronger than in the Confine of Air and Water, and still stronger in the Confine of Air and common Glass or Crystal, and stronger in the Confine of Air and a Diamond. If any of these, and such like transparent Solids, be immerged in Water, its Reflexion becomes, much weaker than before; and still weaker if they be immerged in the more strongly refracting Liquors of well rectified Oil of Vitriol or Spirit of Turpentine. If Water be distinguish'd into two parts by any imaginary Surface, the Reflexion in the Confine of those two parts is none at all. In the Confine of Water and Ice 'tis very little; in that of Water and Oil 'tis something greater; in that of Water and Sal-gem still greater; and in that of Water and Glass, or Crystal or other denser Substances still greater, accordingly as those Mediums differ more or less in their refracting Powers. Hence in the Confine of common Glass and Crystal, there ought to be a weak Reflexion, and a stronger Reflexion in the Confine of common and metalline Glass; though I have not yet tried this. But in the Confine of two Glasses of equal density, there is not any sensible Reflexion; as was shewn in the first Observation. And the same may be understood of the Superficies interceding two Crystals, or two Liquors, or any other Substances in which no Refraction is caused. So then the reason why uniform pellucid Mediums (such as Water, Glass, or Crystal,) have no sensible Reflexion but in their external Superficies, where they are adjacent to other Mediums of a different density, is because all their contiguous parts have one and the same degree of density.

Prop. II.

The least parts of almost all natural Bodies are in some measure transparent: And the Opacity of those Bodies ariseth from the multitude of Reflexions caused in their internal Parts.

That this is so has been observed by others, and will easily be granted by them that have been conversant with Microscopes. And it may be also tried by applying any substance to a hole through which some Light is immitted into a dark Room. For how opake soever that Substance may seem in the open Air, it will by that means appear very manifestly transparent, if it be of a sufficient thinness. Only white metalline Bodies must be excepted, which by reason of their excessive density seem to reflect almost all the Light incident on their first Superficies; unless by solution in Menstruums they be reduced into very small Particles, and then they become transparent.

Prop. III.

Between the parts of opake and colour'd Bodies are many Spaces, either empty, or replenish'd with Mediums of other Densities; as Water between the tinging Corpuscles wherewith any Liquor is impregnated, Air between the aqueous Globules that constitute Clouds or Mists; and for the most part Spaces void of both Air and Water, but yet perhaps not wholly void of all Substance, between the parts of hard Bodies.

The truth of this is evinced by the two precedent Propositions: For by the second Proposition there are many Reflexions made by the internal parts of Bodies, which, by the first Proposition, would not happen if the parts of those Bodies were continued without any such Interstices between them; because Reflexions are caused only in Superficies, which intercede Mediums of a differing density, by Prop. 1.

But farther, that this discontinuity of parts is the principal Cause of the opacity of Bodies, will appear by considering, that opake Substances become transparent by filling their Pores with any Substance of equal or almost equal density with their parts. Thus Paper dipped in Water or Oil, the Oculus Mundi Stone steep'd in Water, Linnen Cloth oiled or varnish'd, and many other Substances soaked in such Liquors as will intimately pervade their little Pores, become by that means more transparent than otherwise; so, on the contrary, the most transparent Substances, may, by evacuating their Pores, or separating their parts, be render'd sufficiently opake; as Salts or wet Paper, or the Oculus Mundi Stone by being dried, Horn by being scraped, Glass by being reduced to Powder, or otherwise flawed; Turpentine by being stirred about with Water till they mix imperfectly, and Water by being form'd into many small Bubbles, either alone in the form of Froth, or by shaking it together with Oil of Turpentine, or Oil Olive, or with some other convenient Liquor, with which it will not perfectly incorporate. And to the increase of the opacity of these Bodies, it conduces something, that by the 23d Observation the Reflexions of very thin transparent Substances are considerably stronger than those made by the same Substances of a greater thickness.

Prop. IV.

The Parts of Bodies and their Interstices must not be less than of some definite bigness, to render them opake and colour'd.

For the opakest Bodies, if their parts be subtilly divided, (as Metals, by being dissolved in acid Menstruums, &c.) become perfectly transparent. And you may also remember, that in the eighth Observation there was no sensible reflexion at the Superficies of the Object-glasses, where they were very near one another, though they did not absolutely touch. And in the 17th Observation the Reflexion of the Water-bubble where it became thinnest was almost insensible, so as to cause very black Spots to appear on the top of the Bubble, by the want of reflected Light.

On these grounds I perceive it is that Water, Salt, Glass, Stones, and such like Substances, are transparent. For, upon divers Considerations, they seem to be as full of Pores or Interstices between their parts as other Bodies are, but yet their Parts and Interstices to be too small to cause Reflexions in their common Surfaces.

Prop. V.

The transparent parts of Bodies, according to their several sizes, reflect Rays of one Colour, and transmit those of another, on the same grounds that thin Plates or Bubbles do reflect or transmit those Rays. And this I take to be the ground of all their Colours.

For if a thinn'd or plated Body, which being of an even thickness, appears all over of one uniform Colour, should be slit into Threads, or broken into Fragments, of the same thickness with the Plate; I see no reason why every Thread or Fragment should not keep its Colour, and by consequence why a heap of those Threads or Fragments should not constitute a Mass or Powder of the same Colour, which the Plate exhibited before it was broken. And the parts of all natural Bodies being like so many Fragments of a Plate, must on the same grounds exhibit the same Colours.

Now, that they do so will appear by the affinity of their Properties. The finely colour'd Feathers of some Birds, and particularly those of Peacocks Tails, do, in the very same part of the Feather, appear of several Colours in several Positions of the Eye, after the very same manner that thin Plates were found to do in the 7th and 19th Observations, and therefore their Colours arise from the thinness of the transparent parts of the Feathers; that is, from the slenderness of the very fine Hairs, or Capillamenta, which grow out of the sides of the grosser lateral Branches or Fibres of those Feathers. And to the same purpose it is, that the Webs of some Spiders, by being spun very fine, have appeared colour'd, as some have observ'd, and that the colour'd Fibres of some Silks, by varying the Position of the Eye, do vary their Colour. Also the Colours of Silks, Cloths, and other Substances, which Water or Oil can intimately penetrate, become more faint and obscure by being immerged in those Liquors, and recover their Vigor again by being dried; much after the manner declared of thin Bodies in the 10th and 21st Observations. Leaf-Gold, some sorts of painted Glass, the Infusion of Lignum Nephriticum, and some other Substances, reflect one Colour, and transmit another; like thin Bodies in the 9th and 20th Observations. And some of those colour'd Powders which Painters use, may have their Colours a little changed, by being very elaborately and finely ground. Where I see not what can be justly pretended for those changes, besides the breaking of their parts into less parts by that contrition, after the same manner that the Colour of a thin Plate is changed by varying its thickness. For which reason also it is that the colour'd Flowers of Plants and Vegetables, by being bruised, usually become more transparent than before, or at least in some degree or other change their Colours. Nor is it much less to my purpose, that, by mixing divers Liquors, very odd and remarkable Productions and Changes of Colours may be effected, of which no cause can be more obvious and rational than that the saline Corpuscles of one Liquor do variously act upon or unite with the tinging Corpuscles of another, so as to make them swell, or shrink, (whereby not only their bulk but their density also may be changed,) or to divide them into smaller Corpuscles, (whereby a colour'd Liquor may become transparent,) or to make many of them associate into one cluster, whereby two transparent Liquors may compose a colour'd one. For we see how apt those saline Menstruums are to penetrate and dissolve Substances to which they are applied, and some of them to precipitate what others dissolve. In like manner, if we consider the various Phænomena of the Atmosphere, we may observe, that when Vapours are first raised, they hinder not the transparency of the Air, being divided into parts too small to cause any Reflexion in their Superficies. But when in order to compose drops of Rain they begin to coalesce and constitute Globules of all intermediate sizes, those Globules, when they become of convenient size to reflect some Colours and transmit others, may constitute Clouds of various Colours according to their sizes. And I see not what can be rationally conceived in so transparent a Substance as Water for the production of these Colours, besides the various sizes of its fluid and globular Parcels.

Prop. VI.

The parts of Bodies on which their Colours depend, are denser than the Medium which pervades their Interstices.

This will appear by considering, that the Colour of a Body depends not only on the Rays which are incident perpendicularly on its parts, but on those also which are incident at all other Angles. And that according to the 7th Observation, a very little variation of obliquity will change the reflected Colour, where the thin Body or small Particles is rarer than the ambient Medium, insomuch that such a small Particle will at diversly oblique Incidences reflect all sorts of Colours, in so great a variety that the Colour resulting from them all, confusedly reflected from a heap of such Particles, must rather be a white or grey than any other Colour, or at best it must be but a very imperfect and dirty Colour. Whereas if the thin Body or small Particle be much denser than the ambient Medium, the Colours, according to the 19th Observation, are so little changed by the variation of obliquity, that the Rays which are reflected least obliquely may predominate over the rest, so much as to cause a heap of such Particles to appear very intensely of their Colour.

It conduces also something to the confirmation of this Proposition, that, according to the 22d Observation, the Colours exhibited by the denser thin Body within the rarer, are more brisk than those exhibited by the rarer within the denser.

Prop. VII.

The bigness of the component parts of natural Bodies may be conjectured by their Colours.

For since the parts of these Bodies, by Prop. 5. do most probably exhibit the same Colours with a Plate of equal thickness, provided they have the same refractive density; and since their parts seem for the most part to have much the same density with Water or Glass, as by many circumstances is obvious to collect; to determine the sizes of those parts, you need only have recourse to the precedent Tables, in which the thickness of Water or Glass exhibiting any Colour is expressed. Thus if it be desired to know the diameter of a Corpuscle, which being of equal density with Glass shall reflect green of the third Order; the Number 16-1/4 shews it to be (16-1/4)/10000 parts of an Inch.

The greatest difficulty is here to know of what Order the Colour of any Body is. And for this end we must have recourse to the 4th and 18th Observations; from whence may be collected these particulars.

Scarlets, and other reds, oranges, and yellows, if they be pure and intense, are most probably of the second order. Those of the first and third order also may be pretty good; only the yellow of the first order is faint, and the orange and red of the third Order have a great Mixture of violet and blue.

There may be good Greens of the fourth Order, but the purest are of the third. And of this Order the green of all Vegetables seems to be, partly by reason of the Intenseness of their Colours, and partly because when they wither some of them turn to a greenish yellow, and others to a more perfect yellow or orange, or perhaps to red, passing first through all the aforesaid intermediate Colours. Which Changes seem to be effected by the exhaling of the Moisture which may leave the tinging Corpuscles more dense, and something augmented by the Accretion of the oily and earthy Part of that Moisture. Now the green, without doubt, is of the same Order with those Colours into which it changeth, because the Changes are gradual, and those Colours, though usually not very full, yet are often too full and lively to be of the fourth Order.

Blues and Purples may be either of the second or third Order, but the best are of the third. Thus the Colour of Violets seems to be of that Order, because their Syrup by acid Liquors turns red, and by urinous and alcalizate turns green. For since it is of the Nature of Acids to dissolve or attenuate, and of Alcalies to precipitate or incrassate, if the Purple Colour of the Syrup was of the second Order, an acid Liquor by attenuating its tinging Corpuscles would change it to a red of the first Order, and an Alcali by incrassating them would change it to a green of the second Order; which red and green, especially the green, seem too imperfect to be the Colours produced by these Changes. But if the said Purple be supposed of the third Order, its Change to red of the second, and green of the third, may without any Inconvenience be allow'd.

If there be found any Body of a deeper and less reddish Purple than that of the Violets, its Colour most probably is of the second Order. But yet there being no Body commonly known whose Colour is constantly more deep than theirs, I have made use of their Name to denote the deepest and least reddish Purples, such as manifestly transcend their Colour in purity.

The blue of the first Order, though very faint and little, may possibly be the Colour of some Substances; and particularly the azure Colour of the Skies seems to be of this Order. For all Vapours when they begin to condense and coalesce into small Parcels, become first of that Bigness, whereby such an Azure must be reflected before they can constitute Clouds of other Colours. And so this being the first Colour which Vapours begin to reflect, it ought to be the Colour of the finest and most transparent Skies, in which Vapours are not arrived to that Grossness requisite to reflect other Colours, as we find it is by Experience.

Whiteness, if most intense and luminous, is that of the first Order, if less strong and luminous, a Mixture of the Colours of several Orders. Of this last kind is the Whiteness of Froth, Paper, Linnen, and most white Substances; of the former I reckon that of white Metals to be. For whilst the densest of Metals, Gold, if foliated, is transparent, and all Metals become transparent if dissolved in Menstruums or vitrified, the Opacity of white Metals ariseth not from their Density alone. They being less dense than Gold would be more transparent than it, did not some other Cause concur with their Density to make them opake. And this Cause I take to be such a Bigness of their Particles as fits them to reflect the white of the first order. For, if they be of other Thicknesses they may reflect other Colours, as is manifest by the Colours which appear upon hot Steel in tempering it, and sometimes upon the Surface of melted Metals in the Skin or Scoria which arises upon them in their cooling. And as the white of the first order is the strongest which can be made by Plates of transparent Substances, so it ought to be stronger in the denser Substances of Metals than in the rarer of Air, Water, and Glass. Nor do I see but that metallick Substances of such a Thickness as may fit them to reflect the white of the first order, may, by reason of their great Density (according to the Tenor of the first of these Propositions) reflect all the Light incident upon them, and so be as opake and splendent as it's possible for any Body to be. Gold, or Copper mix'd with less than half their Weight of Silver, or Tin, or Regulus of Antimony, in fusion, or amalgamed with a very little Mercury, become white; which shews both that the Particles of white Metals have much more Superficies, and so are smaller, than those of Gold and Copper, and also that they are so opake as not to suffer the Particles of Gold or Copper to shine through them. Now it is scarce to be doubted but that the Colours of Gold and Copper are of the second and third order, and therefore the Particles of white Metals cannot be much bigger than is requisite to make them reflect the white of the first order. The Volatility of Mercury argues that they are not much bigger, nor may they be much less, lest they lose their Opacity, and become either transparent as they do when attenuated by Vitrification, or by Solution in Menstruums, or black as they do when ground smaller, by rubbing Silver, or Tin, or Lead, upon other Substances to draw black Lines. The first and only Colour which white Metals take by grinding their Particles smaller, is black, and therefore their white ought to be that which borders upon the black Spot in the Center of the Rings of Colours, that is, the white of the first order. But, if you would hence gather the Bigness of metallick Particles, you must allow for their Density. For were Mercury transparent, its Density is such that the Sine of Incidence upon it (by my Computation) would be to the Sine of its Refraction, as 71 to 20, or 7 to 2. And therefore the Thickness of its Particles, that they may exhibit the same Colours with those of Bubbles of Water, ought to be less than the Thickness of the Skin of those Bubbles in the Proportion of 2 to 7. Whence it's possible, that the Particles of Mercury may be as little as the Particles of some transparent and volatile Fluids, and yet reflect the white of the first order.

Lastly, for the production of black, the Corpuscles must be less than any of those which exhibit Colours. For at all greater sizes there is too much Light reflected to constitute this Colour. But if they be supposed a little less than is requisite to reflect the white and very faint blue of the first order, they will, according to the 4th, 8th, 17th and 18th Observations, reflect so very little Light as to appear intensely black, and yet may perhaps variously refract it to and fro within themselves so long, until it happen to be stifled and lost, by which means they will appear black in all positions of the Eye without any transparency. And from hence may be understood why Fire, and the more subtile dissolver Putrefaction, by dividing the Particles of Substances, turn them to black, why small quantities of black Substances impart their Colour very freely and intensely to other Substances to which they are applied; the minute Particles of these, by reason of their very great number, easily overspreading the gross Particles of others; why Glass ground very elaborately with Sand on a Copper Plate, 'till it be well polish'd, makes the Sand, together with what is worn off from the Glass and Copper, become very black: why black Substances do soonest of all others become hot in the Sun's Light and burn, (which Effect may proceed partly from the multitude of Refractions in a little room, and partly from the easy Commotion of so very small Corpuscles;) and why blacks are usually a little inclined to a bluish Colour. For that they are so may be seen by illuminating white Paper by Light reflected from black Substances. For the Paper will usually appear of a bluish white; and the reason is, that black borders in the obscure blue of the order described in the 18th Observation, and therefore reflects more Rays of that Colour than of any other.

In these Descriptions I have been the more particular, because it is not impossible but that Microscopes may at length be improved to the discovery of the Particles of Bodies on which their Colours depend, if they are not already in some measure arrived to that degree of perfection. For if those Instruments are or can be so far improved as with sufficient distinctness to represent Objects five or six hundred times bigger than at a Foot distance they appear to our naked Eyes, I should hope that we might be able to discover some of the greatest of those Corpuscles. And by one that would magnify three or four thousand times perhaps they might all be discover'd, but those which produce blackness. In the mean while I see nothing material in this Discourse that may rationally be doubted of, excepting this Position: That transparent Corpuscles of the same thickness and density with a Plate, do exhibit the same Colour. And this I would have understood not without some Latitude, as well because those Corpuscles may be of irregular Figures, and many Rays must be obliquely incident on them, and so have a shorter way through them than the length of their Diameters, as because the straitness of the Medium put in on all sides within such Corpuscles may a little alter its Motions or other qualities on which the Reflexion depends. But yet I cannot much suspect the last, because I have observed of some small Plates of Muscovy Glass which were of an even thickness, that through a Microscope they have appeared of the same Colour at their edges and corners where the included Medium was terminated, which they appeared of in other places. However it will add much to our Satisfaction, if those Corpuscles can be discover'd with Microscopes; which if we shall at length attain to, I fear it will be the utmost improvement of this Sense. For it seems impossible to see the more secret and noble Works of Nature within the Corpuscles by reason of their transparency.

Prop. VIII.

The Cause of Reflexion is not the impinging of Light on the solid or impervious parts of Bodies, as is commonly believed.

This will appear by the following Considerations. First, That in the passage of Light out of Glass into Air there is a Reflexion as strong as in its passage out of Air into Glass, or rather a little stronger, and by many degrees stronger than in its passage out of Glass into Water. And it seems not probable that Air should have more strongly reflecting parts than Water or Glass. But if that should possibly be supposed, yet it will avail nothing; for the Reflexion is as strong or stronger when the Air is drawn away from the Glass, (suppose by the Air-Pump invented by Otto Gueriet, and improved and made useful by Mr. Boyle) as when it is adjacent to it. Secondly, If Light in its passage out of Glass into Air be incident more obliquely than at an Angle of 40 or 41 Degrees it is wholly reflected, if less obliquely it is in great measure transmitted. Now it is not to be imagined that Light at one degree of obliquity should meet with Pores enough in the Air to transmit the greater part of it, and at another degree of obliquity should meet with nothing but parts to reflect it wholly, especially considering that in its passage out of Air into Glass, how oblique soever be its Incidence, it finds Pores enough in the Glass to transmit a great part of it. If any Man suppose that it is not reflected by the Air, but by the outmost superficial parts of the Glass, there is still the same difficulty: Besides, that such a Supposition is unintelligible, and will also appear to be false by applying Water behind some part of the Glass instead of Air. For so in a convenient obliquity of the Rays, suppose of 45 or 46 Degrees, at which they are all reflected where the Air is adjacent to the Glass, they shall be in great measure transmitted where the Water is adjacent to it; which argues, that their Reflexion or Transmission depends on the constitution of the Air and Water behind the Glass, and not on the striking of the Rays upon the parts of the Glass. Thirdly, If the Colours made by a Prism placed at the entrance of a Beam of Light into a darken'd Room be successively cast on a second Prism placed at a greater distance from the former, in such manner that they are all alike incident upon it, the second Prism may be so inclined to the incident Rays, that those which are of a blue Colour shall be all reflected by it, and yet those of a red Colour pretty copiously transmitted. Now if the Reflexion be caused by the parts of Air or Glass, I would ask, why at the same Obliquity of Incidence the blue should wholly impinge on those parts, so as to be all reflected, and yet the red find Pores enough to be in a great measure transmitted. Fourthly, Where two Glasses touch one another, there is no sensible Reflexion, as was declared in the first Observation; and yet I see no reason why the Rays should not impinge on the parts of Glass, as much when contiguous to other Glass as when contiguous to Air. Fifthly, When the top of a Water-Bubble (in the 17th Observation,) by the continual subsiding and exhaling of the Water grew very thin, there was such a little and almost insensible quantity of Light reflected from it, that it appeared intensely black; whereas round about that black Spot, where the Water was thicker, the Reflexion was so strong as to make the Water seem very white. Nor is it only at the least thickness of thin Plates or Bubbles, that there is no manifest Reflexion, but at many other thicknesses continually greater and greater. For in the 15th Observation the Rays of the same Colour were by turns transmitted at one thickness, and reflected at another thickness, for an indeterminate number of Successions. And yet in the Superficies of the thinned Body, where it is of any one thickness, there are as many parts for the Rays to impinge on, as where it is of any other thickness. Sixthly, If Reflexion were caused by the parts of reflecting Bodies, it would be impossible for thin Plates or Bubbles, at one and the same place, to reflect the Rays of one Colour, and transmit those of another, as they do according to the 13th and 15th Observations. For it is not to be imagined that at one place the Rays which, for instance, exhibit a blue Colour, should have the fortune to dash upon the parts, and those which exhibit a red to hit upon the Pores of the Body; and then at another place, where the Body is either a little thicker or a little thinner, that on the contrary the blue should hit upon its pores, and the red upon its parts. Lastly, Were the Rays of Light reflected by impinging on the solid parts of Bodies, their Reflexions from polish'd Bodies could not be so regular as they are. For in polishing Glass with Sand, Putty, or Tripoly, it is not to be imagined that those Substances can, by grating and fretting the Glass, bring all its least Particles to an accurate Polish; so that all their Surfaces shall be truly plain or truly spherical, and look all the same way, so as together to compose one even Surface. The smaller the Particles of those Substances are, the smaller will be the Scratches by which they continually fret and wear away the Glass until it be polish'd; but be they never so small they can wear away the Glass no otherwise than by grating and scratching it, and breaking the Protuberances; and therefore polish it no otherwise than by bringing its roughness to a very fine Grain, so that the Scratches and Frettings of the Surface become too small to be visible. And therefore if Light were reflected by impinging upon the solid parts of the Glass, it would be scatter'd as much by the most polish'd Glass as by the roughest. So then it remains a Problem, how Glass polish'd by fretting Substances can reflect Light so regularly as it does. And this Problem is scarce otherwise to be solved, than by saying, that the Reflexion of a Ray is effected, not by a single point of the reflecting Body, but by some power of the Body which is evenly diffused all over its Surface, and by which it acts upon the Ray without immediate Contact. For that the parts of Bodies do act upon Light at a distance shall be shewn hereafter.

Now if Light be reflected, not by impinging on the solid parts of Bodies, but by some other principle; it's probable that as many of its Rays as impinge on the solid parts of Bodies are not reflected but stifled and lost in the Bodies. For otherwise we must allow two sorts of Reflexions. Should all the Rays be reflected which impinge on the internal parts of clear Water or Crystal, those Substances would rather have a cloudy Colour than a clear Transparency. To make Bodies look black, it's necessary that many Rays be stopp'd, retained, and lost in them; and it seems not probable that any Rays can be stopp'd and stifled in them which do not impinge on their parts.

And hence we may understand that Bodies are much more rare and porous than is commonly believed. Water is nineteen times lighter, and by consequence nineteen times rarer than Gold; and Gold is so rare as very readily and without the least opposition to transmit the magnetick Effluvia, and easily to admit Quicksilver into its Pores, and to let Water pass through it. For a concave Sphere of Gold filled with Water, and solder'd up, has, upon pressing the Sphere with great force, let the Water squeeze through it, and stand all over its outside in multitudes of small Drops, like Dew, without bursting or cracking the Body of the Gold, as I have been inform'd by an Eye witness. From all which we may conclude, that Gold has more Pores than solid parts, and by consequence that Water has above forty times more Pores than Parts. And he that shall find out an Hypothesis, by which Water may be so rare, and yet not be capable of compression by force, may doubtless by the same Hypothesis make Gold, and Water, and all other Bodies, as much rarer as he pleases; so that Light may find a ready passage through transparent Substances.

The Magnet acts upon Iron through all dense Bodies not magnetick nor red hot, without any diminution of its Virtue; as for instance, through Gold, Silver, Lead, Glass, Water. The gravitating Power of the Sun is transmitted through the vast Bodies of the Planets without any diminution, so as to act upon all their parts to their very centers with the same Force and according to the same Laws, as if the part upon which it acts were not surrounded with the Body of the Planet, The Rays of Light, whether they be very small Bodies projected, or only Motion or Force propagated, are moved in right Lines; and whenever a Ray of Light is by any Obstacle turned out of its rectilinear way, it will never return into the same rectilinear way, unless perhaps by very great accident. And yet Light is transmitted through pellucid solid Bodies in right Lines to very great distances. How Bodies can have a sufficient quantity of Pores for producing these Effects is very difficult to conceive, but perhaps not altogether impossible. For the Colours of Bodies arise from the Magnitudes of the Particles which reflect them, as was explained above. Now if we conceive these Particles of Bodies to be so disposed amongst themselves, that the Intervals or empty Spaces between them may be equal in magnitude to them all; and that these Particles may be composed of other Particles much smaller, which have as much empty Space between them as equals all the Magnitudes of these smaller Particles: And that in like manner these smaller Particles are again composed of others much smaller, all which together are equal to all the Pores or empty Spaces between them; and so on perpetually till you come to solid Particles, such as have no Pores or empty Spaces within them: And if in any gross Body there be, for instance, three such degrees of Particles, the least of which are solid; this Body will have seven times more Pores than solid Parts. But if there be four such degrees of Particles, the least of which are solid, the Body will have fifteen times more Pores than solid Parts. If there be five degrees, the Body will have one and thirty times more Pores than solid Parts. If six degrees, the Body will have sixty and three times more Pores than solid Parts. And so on perpetually. And there are other ways of conceiving how Bodies may be exceeding porous. But what is really their inward Frame is not yet known to us.

Prop. IX.

Bodies reflect and refract Light by one and the same power, variously exercised in various Circumstances.

This appears by several Considerations. First, Because when Light goes out of Glass into Air, as obliquely as it can possibly do. If its Incidence be made still more oblique, it becomes totally reflected. For the power of the Glass after it has refracted the Light as obliquely as is possible, if the Incidence be still made more oblique, becomes too strong to let any of its Rays go through, and by consequence causes total Reflexions. Secondly, Because Light is alternately reflected and transmitted by thin Plates of Glass for many Successions, accordingly as the thickness of the Plate increases in an arithmetical Progression. For here the thickness of the Glass determines whether that Power by which Glass acts upon Light shall cause it to be reflected, or suffer it to be transmitted. And, Thirdly, because those Surfaces of transparent Bodies which have the greatest refracting power, reflect the greatest quantity of Light, as was shewn in the first Proposition.

Prop. X.

If Light be swifter in Bodies than in Vacuo, in the proportion of the Sines which measure the Refraction of the Bodies, the Forces of the Bodies to reflect and refract Light, are very nearly proportional to the densities of the same Bodies; excepting that unctuous and sulphureous Bodies refract more than others of this same density.

Fig. 8.

Let AB represent the refracting plane Surface of any Body, and IC a Ray incident very obliquely upon the Body in C, so that the Angle ACI may be infinitely little, and let CR be the refracted Ray. From a given Point B perpendicular to the refracting Surface erect BR meeting with the refracting Ray CR in R, and if CR represent the Motion of the refracted Ray, and this Motion be distinguish'd into two Motions CB and BR, whereof CB is parallel to the refracting Plane, and BR perpendicular to it: CB shall represent the Motion of the incident Ray, and BR the Motion generated by the Refraction, as Opticians have of late explain'd.

Now if any Body or Thing, in moving through any Space of a given breadth terminated on both sides by two parallel Planes, be urged forward in all parts of that Space by Forces tending directly forwards towards the last Plane, and before its Incidence on the first Plane, had no Motion towards it, or but an infinitely little one; and if the Forces in all parts of that Space, between the Planes, be at equal distances from the Planes equal to one another, but at several distances be bigger or less in any given Proportion, the Motion generated by the Forces in the whole passage of the Body or thing through that Space shall be in a subduplicate Proportion of the Forces, as Mathematicians will easily understand. And therefore, if the Space of activity of the refracting Superficies of the Body be consider'd as such a Space, the Motion of the Ray generated by the refracting Force of the Body, during its passage through that Space, that is, the Motion BR, must be in subduplicate Proportion of that refracting Force. I say therefore, that the Square of the Line BR, and by consequence the refracting Force of the Body, is very nearly as the density of the same Body. For this will appear by the following Table, wherein the Proportion of the Sines which measure the Refractions of several Bodies, the Square of BR, supposing CB an unite, the Densities of the Bodies estimated by their Specifick Gravities, and their Refractive Power in respect of their Densities are set down in several Columns.

The Refraction of the Air in this Table is determin'd by that of the Atmosphere observed by Astronomers. For, if Light pass through many refracting Substances or Mediums gradually denser and denser, and terminated with parallel Surfaces, the Sum of all the Refractions will be equal to the single Refraction which it would have suffer'd in passing immediately out of the first Medium into the last. And this holds true, though the Number of the refracting Substances be increased to Infinity, and the Distances from one another as much decreased, so that the Light may be refracted in every Point of its Passage, and by continual Refractions bent into a Curve-Line. And therefore the whole Refraction of Light in passing through the Atmosphere from the highest and rarest Part thereof down to the lowest and densest Part, must be equal to the Refraction which it would suffer in passing at like Obliquity out of a Vacuum immediately into Air of equal Density with that in the lowest Part of the Atmosphere.

Now, although a Pseudo-Topaz, a Selenitis, Rock Crystal, Island Crystal, Vulgar Glass (that is, Sand melted together) and Glass of Antimony, which are terrestrial stony alcalizate Concretes, and Air which probably arises from such Substances by Fermentation, be Substances very differing from one another in Density, yet by this Table, they have their refractive Powers almost in the same Proportion to one another as their Densities are, excepting that the Refraction of that strange Substance, Island Crystal is a little bigger than the rest. And particularly Air, which is 3500 Times rarer than the Pseudo-Topaz, and 4400 Times rarer than Glass of Antimony, and 2000 Times rarer than the Selenitis, Glass vulgar, or Crystal of the Rock, has notwithstanding its rarity the same refractive Power in respect of its Density which those very dense Substances have in respect of theirs, excepting so far as those differ from one another.

Again, the Refraction of Camphire, Oil Olive, Linseed Oil, Spirit of Turpentine and Amber, which are fat sulphureous unctuous Bodies, and a Diamond, which probably is an unctuous Substance coagulated, have their refractive Powers in Proportion to one another as their Densities without any considerable Variation. But the refractive Powers of these unctuous Substances are two or three Times greater in respect of their Densities than the refractive Powers of the former Substances in respect of theirs.

Water has a refractive Power in a middle degree between those two sorts of Substances, and probably is of a middle nature. For out of it grow all vegetable and animal Substances, which consist as well of sulphureous fat and inflamable Parts, as of earthy lean and alcalizate ones.

Salts and Vitriols have refractive Powers in a middle degree between those of earthy Substances and Water, and accordingly are composed of those two sorts of Substances. For by distillation and rectification of their Spirits a great Part of them goes into Water, and a great Part remains behind in the form of a dry fix'd Earth capable of Vitrification.

Spirit of Wine has a refractive Power in a middle degree between those of Water and oily Substances, and accordingly seems to be composed of both, united by Fermentation; the Water, by means of some saline Spirits with which 'tis impregnated, dissolving the Oil, and volatizing it by the Action. For Spirit of Wine is inflamable by means of its oily Parts, and being distilled often from Salt of Tartar, grow by every distillation more and more aqueous and phlegmatick. And Chymists observe, that Vegetables (as Lavender, Rue, Marjoram, &c.) distilled per se, before fermentation yield Oils without any burning Spirits, but after fermentation yield ardent Spirits without Oils: Which shews, that their Oil is by fermentation converted into Spirit. They find also, that if Oils be poured in a small quantity upon fermentating Vegetables, they distil over after fermentation in the form of Spirits.

So then, by the foregoing Table, all Bodies seem to have their refractive Powers proportional to their Densities, (or very nearly;) excepting so far as they partake more or less of sulphureous oily Particles, and thereby have their refractive Power made greater or less. Whence it seems rational to attribute the refractive Power of all Bodies chiefly, if not wholly, to the sulphureous Parts with which they abound. For it's probable that all Bodies abound more or less with Sulphurs. And as Light congregated by a Burning-glass acts most upon sulphureous Bodies, to turn them into Fire and Flame; so, since all Action is mutual, Sulphurs ought to act most upon Light. For that the action between Light and Bodies is mutual, may appear from this Consideration; That the densest Bodies which refract and reflect Light most strongly, grow hottest in the Summer Sun, by the action of the refracted or reflected Light.

I have hitherto explain'd the power of Bodies to reflect and refract, and shew'd, that thin transparent Plates, Fibres, and Particles, do, according to their several thicknesses and densities, reflect several sorts of Rays, and thereby appear of several Colours; and by consequence that nothing more is requisite for producing all the Colours of natural Bodies, than the several sizes and densities of their transparent Particles. But whence it is that these Plates, Fibres, and Particles, do, according to their several thicknesses and densities, reflect several sorts of Rays, I have not yet explain'd. To give some insight into this matter, and make way for understanding the next part of this Book, I shall conclude this part with a few more Propositions. Those which preceded respect the nature of Bodies, these the nature of Light: For both must be understood, before the reason of their Actions upon one another can be known. And because the last Proposition depended upon the velocity of Light, I will begin with a Proposition of that kind.

Prop. XI.

Light is propagated from luminous Bodies in time, and spends about seven or eight Minutes of an Hour in passing from the Sun to the Earth.

This was observed first by Roemer, and then by others, by means of the Eclipses of the Satellites of Jupiter. For these Eclipses, when the Earth is between the Sun and Jupiter, happen about seven or eight Minutes sooner than they ought to do by the Tables, and when the Earth is beyond the Sun they happen about seven or eight Minutes later than they ought to do; the reason being, that the Light of the Satellites has farther to go in the latter case than in the former by the Diameter of the Earth's Orbit. Some inequalities of time may arise from the Excentricities of the Orbs of the Satellites; but those cannot answer in all the Satellites, and at all times to the Position and Distance of the Earth from the Sun. The mean motions of Jupiter's Satellites is also swifter in his descent from his Aphelium to his Perihelium, than in his ascent in the other half of his Orb. But this inequality has no respect to the position of the Earth, and in the three interior Satellites is insensible, as I find by computation from the Theory of their Gravity.

Prop. XII.

Every Ray of Light in its passage through any refracting Surface is put into a certain transient Constitution or State, which in the progress of the Ray returns at equal Intervals, and disposes the Ray at every return to be easily transmitted through the next refracting Surface, and between the returns to be easily reflected by it.

This is manifest by the 5th, 9th, 12th, and 15th Observations. For by those Observations it appears, that one and the same sort of Rays at equal Angles of Incidence on any thin transparent Plate, is alternately reflected and transmitted for many Successions accordingly as the thickness of the Plate increases in arithmetical Progression of the Numbers, 0, 1, 2, 3, 4, 5, 6, 7, 8, &c. so that if the first Reflexion (that which makes the first or innermost of the Rings of Colours there described) be made at the thickness 1, the Rays shall be transmitted at the thicknesses 0, 2, 4, 6, 8, 10, 12, &c. and thereby make the central Spot and Rings of Light, which appear by transmission, and be reflected at the thickness 1, 3, 5, 7, 9, 11, &c. and thereby make the Rings which appear by Reflexion. And this alternate Reflexion and Transmission, as I gather by the 24th Observation, continues for above an hundred vicissitudes, and by the Observations in the next part of this Book, for many thousands, being propagated from one Surface of a Glass Plate to the other, though the thickness of the Plate be a quarter of an Inch or above: So that this alternation seems to be propagated from every refracting Surface to all distances without end or limitation.

This alternate Reflexion and Refraction depends on both the Surfaces of every thin Plate, because it depends on their distance. By the 21st Observation, if either Surface of a thin Plate of Muscovy Glass be wetted, the Colours caused by the alternate Reflexion and Refraction grow faint, and therefore it depends on them both.

It is therefore perform'd at the second Surface; for if it were perform'd at the first, before the Rays arrive at the second, it would not depend on the second.

It is also influenced by some action or disposition, propagated from the first to the second, because otherwise at the second it would not depend on the first. And this action or disposition, in its propagation, intermits and returns by equal Intervals, because in all its progress it inclines the Ray at one distance from the first Surface to be reflected by the second, at another to be transmitted by it, and that by equal Intervals for innumerable vicissitudes. And because the Ray is disposed to Reflexion at the distances 1, 3, 5, 7, 9, &c. and to Transmission at the distances 0, 2, 4, 6, 8, 10, &c. (for its transmission through the first Surface, is at the distance 0, and it is transmitted through both together, if their distance be infinitely little or much less than 1) the disposition to be transmitted at the distances 2, 4, 6, 8, 10, &c. is to be accounted a return of the same disposition which the Ray first had at the distance 0, that is at its transmission through the first refracting Surface. All which is the thing I would prove.

What kind of action or disposition this is; Whether it consists in a circulating or a vibrating motion of the Ray, or of the Medium, or something else, I do not here enquire. Those that are averse from assenting to any new Discoveries, but such as they can explain by an Hypothesis, may for the present suppose, that as Stones by falling upon Water put the Water into an undulating Motion, and all Bodies by percussion excite vibrations in the Air; so the Rays of Light, by impinging on any refracting or reflecting Surface, excite vibrations in the refracting or reflecting Medium or Substance, and by exciting them agitate the solid parts of the refracting or reflecting Body, and by agitating them cause the Body to grow warm or hot; that the vibrations thus excited are propagated in the refracting or reflecting Medium or Substance, much after the manner that vibrations are propagated in the Air for causing Sound, and move faster than the Rays so as to overtake them; and that when any Ray is in that part of the vibration which conspires with its Motion, it easily breaks through a refracting Surface, but when it is in the contrary part of the vibration which impedes its Motion, it is easily reflected; and, by consequence, that every Ray is successively disposed to be easily reflected, or easily transmitted, by every vibration which overtakes it. But whether this Hypothesis be true or false I do not here consider. I content my self with the bare Discovery, that the Rays of Light are by some cause or other alternately disposed to be reflected or refracted for many vicissitudes.

DEFINITION.

The returns of the disposition of any Ray to be reflected I will call its Fits of easy Reflexion, and those of its disposition to be transmitted its Fits of easy Transmission, and the space it passes between every return and the next return, the Interval of its Fits.

Prop. XIII.

The reason why the Surfaces of all thick transparent Bodies reflect part of the Light incident on them, and refract the rest, is, that some Rays at their Incidence are in Fits of easy Reflexion, and others in Fits of easy Transmission.

This may be gather'd from the 24th Observation, where the Light reflected by thin Plates of Air and Glass, which to the naked Eye appear'd evenly white all over the Plate, did through a Prism appear waved with many Successions of Light and Darkness made by alternate Fits of easy Reflexion and easy Transmission, the Prism severing and distinguishing the Waves of which the white reflected Light was composed, as was explain'd above.

And hence Light is in Fits of easy Reflexion and easy Transmission, before its Incidence on transparent Bodies. And probably it is put into such fits at its first emission from luminous Bodies, and continues in them during all its progress. For these Fits are of a lasting nature, as will appear by the next part of this Book.

In this Proposition I suppose the transparent Bodies to be thick; because if the thickness of the Body be much less than the Interval of the Fits of easy Reflexion and Transmission of the Rays, the Body loseth its reflecting power. For if the Rays, which at their entering into the Body are put into Fits of easy Transmission, arrive at the farthest Surface of the Body before they be out of those Fits, they must be transmitted. And this is the reason why Bubbles of Water lose their reflecting power when they grow very thin; and why all opake Bodies, when reduced into very small parts, become transparent.

Prop. XIV.

Those Surfaces of transparent Bodies, which if the Ray be in a Fit of Refraction do refract it most strongly, if the Ray be in a Fit of Reflexion do reflect it most easily.

For we shewed above, in Prop. 8. that the cause of Reflexion is not the impinging of Light on the solid impervious parts of Bodies, but some other power by which those solid parts act on Light at a distance. We shewed also in Prop. 9. that Bodies reflect and refract Light by one and the same power, variously exercised in various circumstances; and in Prop. 1. that the most strongly refracting Surfaces reflect the most Light: All which compared together evince and rarify both this and the last Proposition.

Prop. XV.

In any one and the same sort of Rays, emerging in any Angle out of any refracting Surface into one and the same Medium, the Interval of the following Fits of easy Reflexion and Transmission are either accurately or very nearly, as the Rectangle of the Secant of the Angle of Refraction, and of the Secant of another Angle, whose Sine is the first of 106 arithmetical mean Proportionals, between the Sines of Incidence and Refraction, counted from the Sine of Refraction.

This is manifest by the 7th and 19th Observations.

Prop. XVI.

In several sorts of Rays emerging in equal Angles out of any refracting Surface into the same Medium, the Intervals of the following Fits of easy Reflexion and easy Transmission are either accurately, or very nearly, as the Cube-Roots of the Squares of the lengths of a Chord, which found the Notes in an Eight, sol, la, fa, sol, la, mi, fa, sol, with all their intermediate degrees answering to the Colours of those Rays, according to the Analogy described in the seventh Experiment of the second Part of the first Book.

This is manifest by the 13th and 14th Observations.

Prop. XVII.

If Rays of any sort pass perpendicularly into several Mediums, the Intervals of the Fits of easy Reflexion and Transmission in any one Medium, are to those Intervals in any other, as the Sine of Incidence to the Sine of Refraction, when the Rays pass out of the first of those two Mediums into the second.

This is manifest by the 10th Observation.

Prop. XVIII.

If the Rays which paint the Colour in the Confine of yellow and orange pass perpendicularly out of any Medium into Air, the Intervals of their Fits of easy Reflexion are the 1/89000th part of an Inch. And of the same length are the Intervals of their Fits of easy Transmission.

This is manifest by the 6th Observation. From these Propositions it is easy to collect the Intervals of the Fits of easy Reflexion and easy Transmission of any sort of Rays refracted in any angle into any Medium; and thence to know, whether the Rays shall be reflected or transmitted at their subsequent Incidence upon any other pellucid Medium. Which thing, being useful for understanding the next part of this Book, was here to be set down. And for the same reason I add the two following Propositions.

Prop. XIX.

If any sort of Rays falling on the polite Surface of any pellucid Medium be reflected back, the Fits of easy Reflexion, which they have at the point of Reflexion, shall still continue to return; and the Returns shall be at distances from the point of Reflexion in the arithmetical progression of the Numbers 2, 4, 6, 8, 10, 12, &c. and between these Fits the Rays shall be in Fits of easy Transmission.

For since the Fits of easy Reflexion and easy Transmission are of a returning nature, there is no reason why these Fits, which continued till the Ray arrived at the reflecting Medium, and there inclined the Ray to Reflexion, should there cease. And if the Ray at the point of Reflexion was in a Fit of easy Reflexion, the progression of the distances of these Fits from that point must begin from 0, and so be of the Numbers 0, 2, 4, 6, 8, &c. And therefore the progression of the distances of the intermediate Fits of easy Transmission, reckon'd from the same point, must be in the progression of the odd Numbers 1, 3, 5, 7, 9, &c. contrary to what happens when the Fits are propagated from points of Refraction.

Prop. XX.

The Intervals of the Fits of easy Reflexion and easy Transmission, propagated from points of Reflexion into any Medium, are equal to the Intervals of the like Fits, which the same Rays would have, if refracted into the same Medium in Angles of Refraction equal to their Angles of Reflexion.

For when Light is reflected by the second Surface of thin Plates, it goes out afterwards freely at the first Surface to make the Rings of Colours which appear by Reflexion; and, by the freedom of its egress, makes the Colours of these Rings more vivid and strong than those which appear on the other side of the Plates by the transmitted Light. The reflected Rays are therefore in Fits of easy Transmission at their egress; which would not always happen, if the Intervals of the Fits within the Plate after Reflexion were not equal, both in length and number, to their Intervals before it. And this confirms also the proportions set down in the former Proposition. For if the Rays both in going in and out at the first Surface be in Fits of easy Transmission, and the Intervals and Numbers of those Fits between the first and second Surface, before and after Reflexion, be equal, the distances of the Fits of easy Transmission from either Surface, must be in the same progression after Reflexion as before; that is, from the first Surface which transmitted them in the progression of the even Numbers 0, 2, 4, 6, 8, &c. and from the second which reflected them, in that of the odd Numbers 1, 3, 5, 7, &c. But these two Propositions will become much more evident by the Observations in the following part of this Book.

PART IV. Observations concerning the Reflexions and Colours of thick transparent polish'd Plates.

There is no Glass or Speculum how well soever polished, but, besides the Light which it refracts or reflects regularly, scatters every way irregularly a faint Light, by means of which the polish'd Surface, when illuminated in a dark room by a beam of the Sun's Light, may be easily seen in all positions of the Eye. There are certain Phænomena of this scatter'd Light, which when I first observed them, seem'd very strange and surprizing to me. My Observations were as follows.

Obs. 1. The Sun shining into my darken'd Chamber through a hole one third of an Inch wide, I let the intromitted beam of Light fall perpendicularly upon a Glass Speculum ground concave on one side and convex on the other, to a Sphere of five Feet and eleven Inches Radius, and Quick-silver'd over on the convex side. And holding a white opake Chart, or a Quire of Paper at the center of the Spheres to which the Speculum was ground, that is, at the distance of about five Feet and eleven Inches from the Speculum, in such manner, that the beam of Light might pass through a little hole made in the middle of the Chart to the Speculum, and thence be reflected back to the same hole: I observed upon the Chart four or five concentric Irises or Rings of Colours, like Rain-bows, encompassing the hole much after the manner that those, which in the fourth and following Observations of the first part of this Book appear'd between the Object-glasses, encompassed the black Spot, but yet larger and fainter than those. These Rings as they grew larger and larger became diluter and fainter, so that the fifth was scarce visible. Yet sometimes, when the Sun shone very clear, there appear'd faint Lineaments of a sixth and seventh. If the distance of the Chart from the Speculum was much greater or much less than that of six Feet, the Rings became dilute and vanish'd. And if the distance of the Speculum from the Window was much greater than that of six Feet, the reflected beam of Light would be so broad at the distance of six Feet from the Speculum where the Rings appear'd, as to obscure one or two of the innermost Rings. And therefore I usually placed the Speculum at about six Feet from the Window; so that its Focus might there fall in with the center of its concavity at the Rings upon the Chart. And this Posture is always to be understood in the following Observations where no other is express'd.

Obs. 2. The Colours of these Rain-bows succeeded one another from the center outwards, in the same form and order with those which were made in the ninth Observation of the first Part of this Book by Light not reflected, but transmitted through the two Object-glasses. For, first, there was in their common center a white round Spot of faint Light, something broader than the reflected beam of Light, which beam sometimes fell upon the middle of the Spot, and sometimes by a little inclination of the Speculum receded from the middle, and left the Spot white to the center.

This white Spot was immediately encompassed with a dark grey or russet, and that dark grey with the Colours of the first Iris; which Colours on the inside next the dark grey were a little violet and indigo, and next to that a blue, which on the outside grew pale, and then succeeded a little greenish yellow, and after that a brighter yellow, and then on the outward edge of the Iris a red which on the outside inclined to purple.

This Iris was immediately encompassed with a second, whose Colours were in order from the inside outwards, purple, blue, green, yellow, light red, a red mix'd with purple.

Then immediately follow'd the Colours of the third Iris, which were in order outwards a green inclining to purple, a good green, and a red more bright than that of the former Iris.

The fourth and fifth Iris seem'd of a bluish green within, and red without, but so faintly that it was difficult to discern the Colours.

Obs. 3. Measuring the Diameters of these Rings upon the Chart as accurately as I could, I found them also in the same proportion to one another with the Rings made by Light transmitted through the two Object-glasses. For the Diameters of the four first of the bright Rings measured between the brightest parts of their Orbits, at the distance of six Feet from the Speculum were 1-11/16, 2-3/8, 2-11/12, 3-3/8 Inches, whose Squares are in arithmetical progression of the numbers 1, 2, 3, 4. If the white circular Spot in the middle be reckon'd amongst the Rings, and its central Light, where it seems to be most luminous, be put equipollent to an infinitely little Ring; the Squares of the Diameters of the Rings will be in the progression 0, 1, 2, 3, 4, &c. I measured also the Diameters of the dark Circles between these luminous ones, and found their Squares in the progression of the numbers 1/2, 1-1/2, 2-1/2, 3-1/2, &c. the Diameters of the first four at the distance of six Feet from the Speculum, being 1-3/16, 2-1/16, 2-2/3, 3-3/20 Inches. If the distance of the Chart from the Speculum was increased or diminished, the Diameters of the Circles were increased or diminished proportionally.

Obs. 4. By the analogy between these Rings and those described in the Observations of the first Part of this Book, I suspected that there were many more of them which spread into one another, and by interfering mix'd their Colours, and diluted one another so that they could not be seen apart. I viewed them therefore through a Prism, as I did those in the 24th Observation of the first Part of this Book. And when the Prism was so placed as by refracting the Light of their mix'd Colours to separate them, and distinguish the Rings from one another, as it did those in that Observation, I could then see them distincter than before, and easily number eight or nine of them, and sometimes twelve or thirteen. And had not their Light been so very faint, I question not but that I might have seen many more.

Obs. 5. Placing a Prism at the Window to refract the intromitted beam of Light, and cast the oblong Spectrum of Colours on the Speculum: I covered the Speculum with a black Paper which had in the middle of it a hole to let any one of the Colours pass through to the Speculum, whilst the rest were intercepted by the Paper. And now I found Rings of that Colour only which fell upon the Speculum. If the Speculum was illuminated with red, the Rings were totally red with dark Intervals, if with blue they were totally blue, and so of the other Colours. And when they were illuminated with any one Colour, the Squares of their Diameters measured between their most luminous Parts, were in the arithmetical Progression of the Numbers, 0, 1, 2, 3, 4 and the Squares of the Diameters of their dark Intervals in the Progression of the intermediate Numbers 1/2, 1-1/2, 2-1/2, 3-1/2. But if the Colour was varied, they varied their Magnitude. In the red they were largest, in the indigo and violet least, and in the intermediate Colours yellow, green, and blue, they were of several intermediate Bignesses answering to the Colour, that is, greater in yellow than in green, and greater in green than in blue. And hence I knew, that when the Speculum was illuminated with white Light, the red and yellow on the outside of the Rings were produced by the least refrangible Rays, and the blue and violet by the most refrangible, and that the Colours of each Ring spread into the Colours of the neighbouring Rings on either side, after the manner explain'd in the first and second Part of this Book, and by mixing diluted one another so that they could not be distinguish'd, unless near the Center where they were least mix'd. For in this Observation I could see the Rings more distinctly, and to a greater Number than before, being able in the yellow Light to number eight or nine of them, besides a faint shadow of a tenth. To satisfy my self how much the Colours of the several Rings spread into one another, I measured the Diameters of the second and third Rings, and found them when made by the Confine of the red and orange to be to the same Diameters when made by the Confine of blue and indigo, as 9 to 8, or thereabouts. For it was hard to determine this Proportion accurately. Also the Circles made successively by the red, yellow, and green, differ'd more from one another than those made successively by the green, blue, and indigo. For the Circle made by the violet was too dark to be seen. To carry on the Computation, let us therefore suppose that the Differences of the Diameters of the Circles made by the outmost red, the Confine of red and orange, the Confine of orange and yellow, the Confine of yellow and green, the Confine of green and blue, the Confine of blue and indigo, the Confine of indigo and violet, and outmost violet, are in proportion as the Differences of the Lengths of a Monochord which sound the Tones in an Eight; sol, la, fa, sol, la, mi, fa, sol, that is, as the Numbers 1/9, 1/18, 1/12, 1/12, 2/27, 1/27, 1/18. And if the Diameter of the Circle made by the Confine of red and orange be 9A, and that of the Circle made by the Confine of blue and indigo be 8A as above; their difference 9A-8A will be to the difference of the Diameters of the Circles made by the outmost red, and by the Confine of red and orange, as 1/18 + 1/12 + 1/12 + 2/27 to 1/9, that is as 8/27 to 1/9, or 8 to 3, and to the difference of the Circles made by the outmost violet, and by the Confine of blue and indigo, as 1/18 + 1/12 + 1/12 + 2/27 to 1/27 + 1/18, that is, as 8/27 to 5/54, or as 16 to 5. And therefore these differences will be 3/8A and 5/16A. Add the first to 9A and subduct the last from 8A, and you will have the Diameters of the Circles made by the least and most refrangible Rays 75/8A and ((61-1/2)/8)A. These diameters are therefore to one another as 75 to 61-1/2 or 50 to 41, and their Squares as 2500 to 1681, that is, as 3 to 2 very nearly. Which proportion differs not much from the proportion of the Diameters of the Circles made by the outmost red and outmost violet, in the 13th Observation of the first part of this Book.

Obs. 6. Placing my Eye where these Rings appear'd plainest, I saw the Speculum tinged all over with Waves of Colours, (red, yellow, green, blue;) like those which in the Observations of the first part of this Book appeared between the Object-glasses, and upon Bubbles of Water, but much larger. And after the manner of those, they were of various magnitudes in various Positions of the Eye, swelling and shrinking as I moved my Eye this way and that way. They were formed like Arcs of concentrick Circles, as those were; and when my Eye was over against the center of the concavity of the Speculum, (that is, 5 Feet and 10 Inches distant from the Speculum,) their common center was in a right Line with that center of concavity, and with the hole in the Window. But in other postures of my Eye their center had other positions. They appear'd by the Light of the Clouds propagated to the Speculum through the hole in the Window; and when the Sun shone through that hole upon the Speculum, his Light upon it was of the Colour of the Ring whereon it fell, but by its splendor obscured the Rings made by the Light of the Clouds, unless when the Speculum was removed to a great distance from the Window, so that his Light upon it might be broad and faint. By varying the position of my Eye, and moving it nearer to or farther from the direct beam of the Sun's Light, the Colour of the Sun's reflected Light constantly varied upon the Speculum, as it did upon my Eye, the same Colour always appearing to a Bystander upon my Eye which to me appear'd upon the Speculum. And thence I knew that the Rings of Colours upon the Chart were made by these reflected Colours, propagated thither from the Speculum in several Angles, and that their production depended not upon the termination of Light and Shadow.

Obs. 7. By the Analogy of all these Phænomena with those of the like Rings of Colours described in the first part of this Book, it seemed to me that these Colours were produced by this thick Plate of Glass, much after the manner that those were produced by very thin Plates. For, upon trial, I found that if the Quick-silver were rubb'd off from the backside of the Speculum, the Glass alone would cause the same Rings of Colours, but much more faint than before; and therefore the Phænomenon depends not upon the Quick-silver, unless so far as the Quick-silver by increasing the Reflexion of the backside of the Glass increases the Light of the Rings of Colours. I found also that a Speculum of Metal without Glass made some Years since for optical uses, and very well wrought, produced none of those Rings; and thence I understood that these Rings arise not from one specular Surface alone, but depend upon the two Surfaces of the Plate of Glass whereof the Speculum was made, and upon the thickness of the Glass between them. For as in the 7th and 19th Observations of the first part of this Book a thin Plate of Air, Water, or Glass of an even thickness appeared of one Colour when the Rays were perpendicular to it, of another when they were a little oblique, of another when more oblique, of another when still more oblique, and so on; so here, in the sixth Observation, the Light which emerged out of the Glass in several Obliquities, made the Glass appear of several Colours, and being propagated in those Obliquities to the Chart, there painted Rings of those Colours. And as the reason why a thin Plate appeared of several Colours in several Obliquities of the Rays, was, that the Rays of one and the same sort are reflected by the thin Plate at one obliquity and transmitted at another, and those of other sorts transmitted where these are reflected, and reflected where these are transmitted: So the reason why the thick Plate of Glass whereof the Speculum was made did appear of various Colours in various Obliquities, and in those Obliquities propagated those Colours to the Chart, was, that the Rays of one and the same sort did at one Obliquity emerge out of the Glass, at another did not emerge, but were reflected back towards the Quick-silver by the hither Surface of the Glass, and accordingly as the Obliquity became greater and greater, emerged and were reflected alternately for many Successions; and that in one and the same Obliquity the Rays of one sort were reflected, and those of another transmitted. This is manifest by the fifth Observation of this part of this Book. For in that Observation, when the Speculum was illuminated by any one of the prismatick Colours, that Light made many Rings of the same Colour upon the Chart with dark Intervals, and therefore at its emergence out of the Speculum was alternately transmitted and not transmitted from the Speculum to the Chart for many Successions, according to the various Obliquities of its Emergence. And when the Colour cast on the Speculum by the Prism was varied, the Rings became of the Colour cast on it, and varied their bigness with their Colour, and therefore the Light was now alternately transmitted and not transmitted from the Speculum to the Chart at other Obliquities than before. It seemed to me therefore that these Rings were of one and the same original with those of thin Plates, but yet with this difference, that those of thin Plates are made by the alternate Reflexions and Transmissions of the Rays at the second Surface of the Plate, after one passage through it; but here the Rays go twice through the Plate before they are alternately reflected and transmitted. First, they go through it from the first Surface to the Quick-silver, and then return through it from the Quick-silver to the first Surface, and there are either transmitted to the Chart or reflected back to the Quick-silver, accordingly as they are in their Fits of easy Reflexion or Transmission when they arrive at that Surface. For the Intervals of the Fits of the Rays which fall perpendicularly on the Speculum, and are reflected back in the same perpendicular Lines, by reason of the equality of these Angles and Lines, are of the same length and number within the Glass after Reflexion as before, by the 19th Proposition of the third part of this Book. And therefore since all the Rays that enter through the first Surface are in their Fits of easy Transmission at their entrance, and as many of these as are reflected by the second are in their Fits of easy Reflexion there, all these must be again in their Fits of easy Transmission at their return to the first, and by consequence there go out of the Glass to the Chart, and form upon it the white Spot of Light in the center of the Rings. For the reason holds good in all sorts of Rays, and therefore all sorts must go out promiscuously to that Spot, and by their mixture cause it to be white. But the Intervals of the Fits of those Rays which are reflected more obliquely than they enter, must be greater after Reflexion than before, by the 15th and 20th Propositions. And thence it may happen that the Rays at their return to the first Surface, may in certain Obliquities be in Fits of easy Reflexion, and return back to the Quick-silver, and in other intermediate Obliquities be again in Fits of easy Transmission, and so go out to the Chart, and paint on it the Rings of Colours about the white Spot. And because the Intervals of the Fits at equal obliquities are greater and fewer in the less refrangible Rays, and less and more numerous in the more refrangible, therefore the less refrangible at equal obliquities shall make fewer Rings than the more refrangible, and the Rings made by those shall be larger than the like number of Rings made by these; that is, the red Rings shall be larger than the yellow, the yellow than the green, the green than the blue, and the blue than the violet, as they were really found to be in the fifth Observation. And therefore the first Ring of all Colours encompassing the white Spot of Light shall be red without any violet within, and yellow, and green, and blue in the middle, as it was found in the second Observation; and these Colours in the second Ring, and those that follow, shall be more expanded, till they spread into one another, and blend one another by interfering.

These seem to be the reasons of these Rings in general; and this put me upon observing the thickness of the Glass, and considering whether the dimensions and proportions of the Rings may be truly derived from it by computation.

Obs. 8. I measured therefore the thickness of this concavo-convex Plate of Glass, and found it every where 1/4 of an Inch precisely. Now, by the sixth Observation of the first Part of this Book, a thin Plate of Air transmits the brightest Light of the first Ring, that is, the bright yellow, when its thickness is the 1/89000th part of an Inch; and by the tenth Observation of the same Part, a thin Plate of Glass transmits the same Light of the same Ring, when its thickness is less in proportion of the Sine of Refraction to the Sine of Incidence, that is, when its thickness is the 11/1513000th or 1/137545th part of an Inch, supposing the Sines are as 11 to 17. And if this thickness be doubled, it transmits the same bright Light of the second Ring; if tripled, it transmits that of the third, and so on; the bright yellow Light in all these cases being in its Fits of Transmission. And therefore if its thickness be multiplied 34386 times, so as to become 1/4 of an Inch, it transmits the same bright Light of the 34386th Ring. Suppose this be the bright yellow Light transmitted perpendicularly from the reflecting convex side of the Glass through the concave side to the white Spot in the center of the Rings of Colours on the Chart: And by a Rule in the 7th and 19th Observations in the first Part of this Book, and by the 15th and 20th Propositions of the third Part of this Book, if the Rays be made oblique to the Glass, the thickness of the Glass requisite to transmit the same bright Light of the same Ring in any obliquity, is to this thickness of 1/4 of an Inch, as the Secant of a certain Angle to the Radius, the Sine of which Angle is the first of an hundred and six arithmetical Means between the Sines of Incidence and Refraction, counted from the Sine of Incidence when the Refraction is made out of any plated Body into any Medium encompassing it; that is, in this case, out of Glass into Air. Now if the thickness of the Glass be increased by degrees, so as to bear to its first thickness, (viz. that of a quarter of an Inch,) the Proportions which 34386 (the number of Fits of the perpendicular Rays in going through the Glass towards the white Spot in the center of the Rings,) hath to 34385, 34384, 34383, and 34382, (the numbers of the Fits of the oblique Rays in going through the Glass towards the first, second, third, and fourth Rings of Colours,) and if the first thickness be divided into 100000000 equal parts, the increased thicknesses will be 100002908, 100005816, 100008725, and 100011633, and the Angles of which these thicknesses are Secants will be 26´ 13´´, 37´ 5´´, 45´ 6´´, and 52´ 26´´, the Radius being 100000000; and the Sines of these Angles are 762, 1079, 1321, and 1525, and the proportional Sines of Refraction 1172, 1659, 2031, and 2345, the Radius being 100000. For since the Sines of Incidence out of Glass into Air are to the Sines of Refraction as 11 to 17, and to the above-mentioned Secants as 11 to the first of 106 arithmetical Means between 11 and 17, that is, as 11 to 11-6/106, those Secants will be to the Sines of Refraction as 11-6/106, to 17, and by this Analogy will give these Sines. So then, if the obliquities of the Rays to the concave Surface of the Glass be such that the Sines of their Refraction in passing out of the Glass through that Surface into the Air be 1172, 1659, 2031, 2345, the bright Light of the 34386th Ring shall emerge at the thicknesses of the Glass, which are to 1/4 of an Inch as 34386 to 34385, 34384, 34383, 34382, respectively. And therefore, if the thickness in all these Cases be 1/4 of an Inch (as it is in the Glass of which the Speculum was made) the bright Light of the 34385th Ring shall emerge where the Sine of Refraction is 1172, and that of the 34384th, 34383th, and 34382th Ring where the Sine is 1659, 2031, and 2345 respectively. And in these Angles of Refraction the Light of these Rings shall be propagated from the Speculum to the Chart, and there paint Rings about the white central round Spot of Light which we said was the Light of the 34386th Ring. And the Semidiameters of these Rings shall subtend the Angles of Refraction made at the Concave-Surface of the Speculum, and by consequence their Diameters shall be to the distance of the Chart from the Speculum as those Sines of Refraction doubled are to the Radius, that is, as 1172, 1659, 2031, and 2345, doubled are to 100000. And therefore, if the distance of the Chart from the Concave-Surface of the Speculum be six Feet (as it was in the third of these Observations) the Diameters of the Rings of this bright yellow Light upon the Chart shall be 1'688, 2'389, 2'925, 3'375 Inches: For these Diameters are to six Feet, as the above-mention'd Sines doubled are to the Radius. Now, these Diameters of the bright yellow Rings, thus found by Computation are the very same with those found in the third of these Observations by measuring them, viz. with 1-11/16, 2-3/8, 2-11/12, and 3-3/8 Inches, and therefore the Theory of deriving these Rings from the thickness of the Plate of Glass of which the Speculum was made, and from the Obliquity of the emerging Rays agrees with the Observation. In this Computation I have equalled the Diameters of the bright Rings made by Light of all Colours, to the Diameters of the Rings made by the bright yellow. For this yellow makes the brightest Part of the Rings of all Colours. If you desire the Diameters of the Rings made by the Light of any other unmix'd Colour, you may find them readily by putting them to the Diameters of the bright yellow ones in a subduplicate Proportion of the Intervals of the Fits of the Rays of those Colours when equally inclined to the refracting or reflecting Surface which caused those Fits, that is, by putting the Diameters of the Rings made by the Rays in the Extremities and Limits of the seven Colours, red, orange, yellow, green, blue, indigo, violet, proportional to the Cube-roots of the Numbers, 1, 8/9, 5/6, 3/4, 2/3, 3/5, 9/16, 1/2, which express the Lengths of a Monochord sounding the Notes in an Eighth: For by this means the Diameters of the Rings of these Colours will be found pretty nearly in the same Proportion to one another, which they ought to have by the fifth of these Observations.

And thus I satisfy'd my self, that these Rings were of the same kind and Original with those of thin Plates, and by consequence that the Fits or alternate Dispositions of the Rays to be reflected and transmitted are propagated to great distances from every reflecting and refracting Surface. But yet to put the matter out of doubt, I added the following Observation.

Obs. 9. If these Rings thus depend on the thickness of the Plate of Glass, their Diameters at equal distances from several Speculums made of such concavo-convex Plates of Glass as are ground on the same Sphere, ought to be reciprocally in a subduplicate Proportion of the thicknesses of the Plates of Glass. And if this Proportion be found true by experience it will amount to a demonstration that these Rings (like those formed in thin Plates) do depend on the thickness of the Glass. I procured therefore another concavo-convex Plate of Glass ground on both sides to the same Sphere with the former Plate. Its thickness was 5/62 Parts of an Inch; and the Diameters of the three first bright Rings measured between the brightest Parts of their Orbits at the distance of six Feet from the Glass were 3·4-1/6·5-1/8· Inches. Now, the thickness of the other Glass being 1/4 of an Inch was to the thickness of this Glass as 1/4 to 5/62, that is as 31 to 10, or 310000000 to 100000000, and the Roots of these Numbers are 17607 and 10000, and in the Proportion of the first of these Roots to the second are the Diameters of the bright Rings made in this Observation by the thinner Glass, 3·4-1/6·5-1/8, to the Diameters of the same Rings made in the third of these Observations by the thicker Glass 1-11/16, 2-3/8. 2-11/12, that is, the Diameters of the Rings are reciprocally in a subduplicate Proportion of the thicknesses of the Plates of Glass.

So then in Plates of Glass which are alike concave on one side, and alike convex on the other side, and alike quick-silver'd on the convex sides, and differ in nothing but their thickness, the Diameters of the Rings are reciprocally in a subduplicate Proportion of the thicknesses of the Plates. And this shews sufficiently that the Rings depend on both the Surfaces of the Glass. They depend on the convex Surface, because they are more luminous when that Surface is quick-silver'd over than when it is without Quick-silver. They depend also upon the concave Surface, because without that Surface a Speculum makes them not. They depend on both Surfaces, and on the distances between them, because their bigness is varied by varying only that distance. And this dependence is of the same kind with that which the Colours of thin Plates have on the distance of the Surfaces of those Plates, because the bigness of the Rings, and their Proportion to one another, and the variation of their bigness arising from the variation of the thickness of the Glass, and the Orders of their Colours, is such as ought to result from the Propositions in the end of the third Part of this Book, derived from the Phænomena of the Colours of thin Plates set down in the first Part.

There are yet other Phænomena of these Rings of Colours, but such as follow from the same Propositions, and therefore confirm both the Truth of those Propositions, and the Analogy between these Rings and the Rings of Colours made by very thin Plates. I shall subjoin some of them.

Obs. 10. When the beam of the Sun's Light was reflected back from the Speculum not directly to the hole in the Window, but to a place a little distant from it, the common center of that Spot, and of all the Rings of Colours fell in the middle way between the beam of the incident Light, and the beam of the reflected Light, and by consequence in the center of the spherical concavity of the Speculum, whenever the Chart on which the Rings of Colours fell was placed at that center. And as the beam of reflected Light by inclining the Speculum receded more and more from the beam of incident Light and from the common center of the colour'd Rings between them, those Rings grew bigger and bigger, and so also did the white round Spot, and new Rings of Colours emerged successively out of their common center, and the white Spot became a white Ring encompassing them; and the incident and reflected beams of Light always fell upon the opposite parts of this white Ring, illuminating its Perimeter like two mock Suns in the opposite parts of an Iris. So then the Diameter of this Ring, measured from the middle of its Light on one side to the middle of its Light on the other side, was always equal to the distance between the middle of the incident beam of Light, and the middle of the reflected beam measured at the Chart on which the Rings appeared: And the Rays which form'd this Ring were reflected by the Speculum in Angles equal to their Angles of Incidence, and by consequence to their Angles of Refraction at their entrance into the Glass, but yet their Angles of Reflexion were not in the same Planes with their Angles of Incidence.

Obs. 11. The Colours of the new Rings were in a contrary order to those of the former, and arose after this manner. The white round Spot of Light in the middle of the Rings continued white to the center till the distance of the incident and reflected beams at the Chart was about 7/8 parts of an Inch, and then it began to grow dark in the middle. And when that distance was about 1-3/16 of an Inch, the white Spot was become a Ring encompassing a dark round Spot which in the middle inclined to violet and indigo. And the luminous Rings encompassing it were grown equal to those dark ones which in the four first Observations encompassed them, that is to say, the white Spot was grown a white Ring equal to the first of those dark Rings, and the first of those luminous Rings was now grown equal to the second of those dark ones, and the second of those luminous ones to the third of those dark ones, and so on. For the Diameters of the luminous Rings were now 1-3/16, 2-1/16, 2-2/3, 3-3/20, &c. Inches.

When the distance between the incident and reflected beams of Light became a little bigger, there emerged out of the middle of the dark Spot after the indigo a blue, and then out of that blue a pale green, and soon after a yellow and red. And when the Colour at the center was brightest, being between yellow and red, the bright Rings were grown equal to those Rings which in the four first Observations next encompassed them; that is to say, the white Spot in the middle of those Rings was now become a white Ring equal to the first of those bright Rings, and the first of those bright ones was now become equal to the second of those, and so on. For the Diameters of the white Ring, and of the other luminous Rings encompassing it, were now 1-11/16, 2-3/8, 2-11/12, 3-3/8, &c. or thereabouts.

When the distance of the two beams of Light at the Chart was a little more increased, there emerged out of the middle in order after the red, a purple, a blue, a green, a yellow, and a red inclining much to purple, and when the Colour was brightest being between yellow and red, the former indigo, blue, green, yellow and red, were become an Iris or Ring of Colours equal to the first of those luminous Rings which appeared in the four first Observations, and the white Ring which was now become the second of the luminous Rings was grown equal to the second of those, and the first of those which was now become the third Ring was become equal to the third of those, and so on. For their Diameters were 1-11/16, 2-3/8, 2-11/12, 3-3/8 Inches, the distance of the two beams of Light, and the Diameter of the white Ring being 2-3/8 Inches.

When these two beams became more distant there emerged out of the middle of the purplish red, first a darker round Spot, and then out of the middle of that Spot a brighter. And now the former Colours (purple, blue, green, yellow, and purplish red) were become a Ring equal to the first of the bright Rings mentioned in the four first Observations, and the Rings about this Ring were grown equal to the Rings about that respectively; the distance between the two beams of Light and the Diameter of the white Ring (which was now become the third Ring) being about 3 Inches.

The Colours of the Rings in the middle began now to grow very dilute, and if the distance between the two Beams was increased half an Inch, or an Inch more, they vanish'd whilst the white Ring, with one or two of the Rings next it on either side, continued still visible. But if the distance of the two beams of Light was still more increased, these also vanished: For the Light which coming from several parts of the hole in the Window fell upon the Speculum in several Angles of Incidence, made Rings of several bignesses, which diluted and blotted out one another, as I knew by intercepting some part of that Light. For if I intercepted that part which was nearest to the Axis of the Speculum the Rings would be less, if the other part which was remotest from it they would be bigger.

Obs. 12. When the Colours of the Prism were cast successively on the Speculum, that Ring which in the two last Observations was white, was of the same bigness in all the Colours, but the Rings without it were greater in the green than in the blue, and still greater in the yellow, and greatest in the red. And, on the contrary, the Rings within that white Circle were less in the green than in the blue, and still less in the yellow, and least in the red. For the Angles of Reflexion of those Rays which made this Ring, being equal to their Angles of Incidence, the Fits of every reflected Ray within the Glass after Reflexion are equal in length and number to the Fits of the same Ray within the Glass before its Incidence on the reflecting Surface. And therefore since all the Rays of all sorts at their entrance into the Glass were in a Fit of Transmission, they were also in a Fit of Transmission at their returning to the same Surface after Reflexion; and by consequence were transmitted, and went out to the white Ring on the Chart. This is the reason why that Ring was of the same bigness in all the Colours, and why in a mixture of all it appears white. But in Rays which are reflected in other Angles, the Intervals of the Fits of the least refrangible being greatest, make the Rings of their Colour in their progress from this white Ring, either outwards or inwards, increase or decrease by the greatest steps; so that the Rings of this Colour without are greatest, and within least. And this is the reason why in the last Observation, when the Speculum was illuminated with white Light, the exterior Rings made by all Colours appeared red without and blue within, and the interior blue without and red within.

These are the Phænomena of thick convexo-concave Plates of Glass, which are every where of the same thickness. There are yet other Phænomena when these Plates are a little thicker on one side than on the other, and others when the Plates are more or less concave than convex, or plano-convex, or double-convex. For in all these cases the Plates make Rings of Colours, but after various manners; all which, so far as I have yet observed, follow from the Propositions in the end of the third part of this Book, and so conspire to confirm the truth of those Propositions. But the Phænomena are too various, and the Calculations whereby they follow from those Propositions too intricate to be here prosecuted. I content my self with having prosecuted this kind of Phænomena so far as to discover their Cause, and by discovering it to ratify the Propositions in the third Part of this Book.

Obs. 13. As Light reflected by a Lens quick-silver'd on the backside makes the Rings of Colours above described, so it ought to make the like Rings of Colours in passing through a drop of Water. At the first Reflexion of the Rays within the drop, some Colours ought to be transmitted, as in the case of a Lens, and others to be reflected back to the Eye. For instance, if the Diameter of a small drop or globule of Water be about the 500th part of an Inch, so that a red-making Ray in passing through the middle of this globule has 250 Fits of easy Transmission within the globule, and that all the red-making Rays which are at a certain distance from this middle Ray round about it have 249 Fits within the globule, and all the like Rays at a certain farther distance round about it have 248 Fits, and all those at a certain farther distance 247 Fits, and so on; these concentrick Circles of Rays after their transmission, falling on a white Paper, will make concentrick Rings of red upon the Paper, supposing the Light which passes through one single globule, strong enough to be sensible. And, in like manner, the Rays of other Colours will make Rings of other Colours. Suppose now that in a fair Day the Sun shines through a thin Cloud of such globules of Water or Hail, and that the globules are all of the same bigness; and the Sun seen through this Cloud shall appear encompassed with the like concentrick Rings of Colours, and the Diameter of the first Ring of red shall be 7-1/4 Degrees, that of the second 10-1/4 Degrees, that of the third 12 Degrees 33 Minutes. And accordingly as the Globules of Water are bigger or less, the Rings shall be less or bigger. This is the Theory, and Experience answers it. For in June 1692, I saw by reflexion in a Vessel of stagnating Water three Halos, Crowns, or Rings of Colours about the Sun, like three little Rain-bows, concentrick to his Body. The Colours of the first or innermost Crown were blue next the Sun, red without, and white in the middle between the blue and red. Those of the second Crown were purple and blue within, and pale red without, and green in the middle. And those of the third were pale blue within, and pale red without; these Crowns enclosed one another immediately, so that their Colours proceeded in this continual order from the Sun outward: blue, white, red; purple, blue, green, pale yellow and red; pale blue, pale red. The Diameter of the second Crown measured from the middle of the yellow and red on one side of the Sun, to the middle of the same Colour on the other side was 9-1/3 Degrees, or thereabouts. The Diameters of the first and third I had not time to measure, but that of the first seemed to be about five or six Degrees, and that of the third about twelve. The like Crowns appear sometimes about the Moon; for in the beginning of the Year 1664, Febr. 19th at Night, I saw two such Crowns about her. The Diameter of the first or innermost was about three Degrees, and that of the second about five Degrees and an half. Next about the Moon was a Circle of white, and next about that the inner Crown, which was of a bluish green within next the white, and of a yellow and red without, and next about these Colours were blue and green on the inside of the outward Crown, and red on the outside of it. At the same time there appear'd a Halo about 22 Degrees 35´ distant from the center of the Moon. It was elliptical, and its long Diameter was perpendicular to the Horizon, verging below farthest from the Moon. I am told that the Moon has sometimes three or more concentrick Crowns of Colours encompassing one another next about her Body. The more equal the globules of Water or Ice are to one another, the more Crowns of Colours will appear, and the Colours will be the more lively. The Halo at the distance of 22-1/2 Degrees from the Moon is of another sort. By its being oval and remoter from the Moon below than above, I conclude, that it was made by Refraction in some sort of Hail or Snow floating in the Air in an horizontal posture, the refracting Angle being about 58 or 60 Degrees.

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